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In polymer chemistry, emulsion polymerization is a type of radical polymerization that usually starts with an emulsion incorporating water, monomers, and surfactants.The most common type of emulsion polymerization is an oil-in-water emulsion, in which droplets of monomer (the oil) are emulsified (with surfactants) in a continuous phase of water.
For example, for the polymerization of ethylene, 93.6 kJ of energy are released per mole of monomer. [8] The manner in which polymerization is conducted is a highly evolved technology. Methods include emulsion polymerization, solution polymerization, suspension polymerization, and precipitation polymerization.
An emulsion is a mixture of two or more liquids that are normally immiscible (unmixable or unblendable) owing to liquid-liquid phase separation.Emulsions are part of a more general class of two-phase systems of matter called colloids.
For example, a mixture that is 60% Water and 40% Oil can form an emulsion where the water is the dispersed phase and the oil is the continuous phase if the emulsifier is more soluble in the oil. This is because the continuous phase is the phase that can coalesce the fastest upon mixing, which means it is the phase that can diffuse the ...
In emulsion polymerization, starve-fed refers to a method of monomer addition where the monomer is introduced gradually into the reaction vessel at a rate that allows the majority of monomer to be consumed by the reaction before more is added.
While third phase is a term for an unwanted emulsion, a stable emulsion is wanted in emulsion polymerization all the things which can be used to make a stable 'emulsion' for a latex synthesis can prove to encourage a third phase to form. One term for the third phase found in PUREX plants is crud (Chalk River Unknown Deposit).
Robert Goulston Gilbert (born 1946) is a polymer chemist whose most significant contributions have been in the field of emulsion polymerisation.In 1970, he gained his PhD from the Australian National University, and worked at the University of Sydney from then until 2006.
Emulsions are thermodynamically unstable liquid/liquid dispersions that are stabilized. [1] Emulsion dispersion is not about reactor blends for which one polymer is polymerized from its monomer in the presence of the other polymers; emulsion dispersion is a novel method of choice for the preparation of homogeneous blends of thermoplastic and elastomer. [2]