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Polybutadiene [butadiene rubber, BR] is a synthetic rubber. It offers high elasticity, high resistance to wear, good strength even without fillers, and excellent abrasion resistance when filled and vulcanized. "Polybutadiene" is a collective name for homopolymers formed from the polymerization of the monomer 1,3-butadiene.
Hydroxyl-terminated polybutadiene (HTPB) is an oligomer of butadiene terminated at each end with a hydroxyl functional group. It reacts with isocyanates to form polyurethane polymers. HTPB is a translucent liquid with a color similar to wax paper and a viscosity similar to corn syrup.
Most polyolefin are made by treating the monomer with metal-containing catalysts. The reaction is highly exothermic. Traditionally, Ziegler-Natta catalysts are used. Named after the Nobelists Karl Ziegler and Giulio Natta, these catalysts are prepared by treating titanium chlorides with organoaluminium compounds, such as triethylaluminium.
Isotactic PB-1 is produced commercially using two types of heterogeneous Ziegler–Natta catalysts. [3] The first type of catalyst contains two components, a solid pre-catalyst, the δ-crystalline form of TiCl 3, and solution of an organoaluminum cocatalyst, such as Al(C 2 H 5) 3.
Polybutadiene acrylonitrile (PBAN) [1] copolymer, also noted as polybutadiene—acrylic acid—acrylonitrile terpolymer [2] is a copolymer compound used most frequently as a rocket propellant fuel mixed with ammonium perchlorate oxidizer. [3] It was the binder formulation widely used on the 1960s–1970s big boosters (e.g., Titan III and Space ...
For example, polystyrene chains may be grafted onto polybutadiene, a synthetic rubber which retains one reactive C=C double bond per repeat unit. The polybutadiene is dissolved in styrene, which is then subjected to free-radical polymerization. The growing chains can add across the double bonds of rubber molecules forming polystyrene branches.
Polybutene is an organic polymer made from a mixture of 1-butene, 2-butene, and isobutylene.Ethylene steam cracker C4s are also used as supplemental feed for polybutene. It is similar to polyisobutylene (PIB), which is produced from essentially pure isobutylene made in a C4 complex of a major refinery.
Nitrile rubber was developed in 1931 at BASF and Bayer, then part of chemical conglomerate IG Farben.The first commercial production began in Germany in 1935. [2] [3]IG Farben plant under construction approximately 10 kilometres (6.2 mi) from Auschwitz, 1942