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Cyclohexanone is produced by the oxidation of cyclohexane in air, typically using cobalt catalysts: [11]. C 6 H 12 + O 2 → (CH 2) 5 CO + H 2 O. This process forms cyclohexanol as a by-product, and this mixture, called "KA Oil" for ketone-alcohol oil, is the main feedstock for the production of adipic acid.
It can be obtained from cyclohexanone by α-bromination followed by treatment with base. Hydrolysis of 3-chloro cyclohexene followed by oxidation of the cyclohexenol is yet another route. Cyclohexenone is produced industrially by catalytic oxidation of cyclohexene, for example with hydrogen peroxide and vanadium catalysts. Several patents ...
Cyclohexylbenzene is a precursor to both phenol and cyclohexanone. [7] Hydration of cyclohexene gives cyclohexanol, which can be dehydrogenated to give cyclohexanone, a precursor to caprolactam. [8] The oxidative cleavage of cyclohexene gives adipic acid. Hydrogen peroxide is used as the oxidant in the presence of a tungsten catalyst. [9]
1,1 ′-Dihydroxydicyclohexyl peroxide is an organic compound with the formula (C 6 H 10 OH) 2 O 2.It is one of the peroxides derived from the reaction of cyclohexanone and hydrogen peroxide.
A short overview and an investigation of the oxidation of cyclohexene by hydrogen peroxide is given in the literature. [6] In recent times the catalytic oxidation of cyclohexene by (immobilized) metalloporphyrin complexes has been found to be an efficient way. [7] [8]
Isophorone undergoes reactions characteristic of an α,β-unsaturated ketone. Hydrogenation gives the cyclohexanone derivative. Epoxidation with basic hydrogen peroxide affords the oxide. [5] Isophorone is degraded by attack of hydroxyl radicals. [6]
The peroxide group is marked in blue. R, R 1 and R 2 mark hydrocarbon moieties. The most common peroxide is hydrogen peroxide (H 2 O 2), colloquially known simply as "peroxide". It is marketed as solutions in water at various concentrations. Many organic peroxides are known as well. In addition to hydrogen peroxide, some other major classes of ...
It is produced industrially by the hydrogenation of cyclohexanone in the presence of hydrogen sulfide over a metal sulfide catalyst: C 6 H 10 O + H 2 S + H 2 → C 6 H 11 SH + H 2 O. It is also obtained by the addition of hydrogen sulfide to cyclohexene in the presence of nickel sulfide. [2]