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The vanadium redox battery, a type of flow battery, is an electrochemical cell consisting of aqueous vanadium ions in different oxidation states. [ 88 ] [ 89 ] Batteries of this type were first proposed in the 1930s and developed commercially from the 1980s onwards.
Vanadium pentoxide is a commercially important catalyst for the production of sulfuric acid, a reaction that exploits the ability of vanadium oxides to undergo redox reactions. [2] The vanadium redox battery utilizes all four oxidation states: one electrode uses the +5/+4 couple and the other uses the +3/+2 couple. Conversion of these oxidation ...
Vanadium(V) oxide (vanadia) is the inorganic compound with the formula V 2 O 5. Commonly known as vanadium pentoxide, it is a dark yellow solid, although when freshly precipitated from aqueous solution, its colour is deep orange. Because of its high oxidation state, it is both an amphoteric oxide and an oxidizing agent.
Oxidation states are typically represented by integers which may be positive, zero, or negative. In some cases, the average oxidation state of an element is a fraction, such as 8 / 3 for iron in magnetite Fe 3 O 4 . The highest known oxidation state is reported to be +9, displayed by iridium in the tetroxoiridium(IX) cation (IrO + 4). [1]
Vanadium(V) oxide or vanadium pentoxide is the most common, being precursor to most alloys and compounds of vanadium, and is also a widely used industrial catalyst. [29] Niobium forms oxides in the oxidation states +5 (Nb 2 O 5), [30] +4 (NbO 2), and the rarer oxidation state, +2 . [31]
The oxidation states are also maintained in articles of the elements (of course), and systematically in the table {{Infobox element/symbol-to-oxidation-state}} See also [ edit ]
In chemistry, a vanadate is an anionic coordination complex of vanadium. Often vanadate refers to oxoanions of vanadium, most of which exist in its highest oxidation state of +5. The complexes [V(CN) 6] 3− and [V 2 Cl 9] 3− are referred to as hexacyanovanadate(III) and nonachlorodivanadate(III), respectively.
Vanadium(III) oxide is the inorganic compound with the formula V 2 O 3. It is a black solid prepared by reduction of V 2 O 5 with hydrogen or carbon monoxide . [ 3 ] [ 4 ] It is a basic oxide dissolving in acids to give solutions of vanadium (III) complexes. [ 4 ]