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Considering the industrial production of hydrogen, and using current best processes for water electrolysis (PEM or alkaline electrolysis) which have an effective electrical efficiency of 70–80%, [68] [73] [74] producing 1 kg of hydrogen (which has a specific energy of 143 MJ/kg) requires 50–55 kW⋅h (180–200 MJ) of electricity.
Ultrahigh-pressure electrolysis is high-pressure electrolysis operating at 340–690 bars (5,000–10,000 psi). [8] At ultra-high pressures the water solubility and cross-permeation across the membrane of H 2 and O 2 is affecting hydrogen purity, modified PEMs are used to reduce cross-permeation in combination with catalytic H 2 /O 2 recombiners to maintain H 2 levels in O 2 and O 2 levels in ...
High pressure electrolysis is the electrolysis of water by decomposition of water (H 2 O) into oxygen (O 2) and hydrogen gas (H 2) by means of an electric current being passed through the water. The difference with a standard electrolyzer is the compressed hydrogen output around 120–200 bar (1740–2900 psi , 12–20 MPa ). [ 146 ]
The produced hydrogen and oxygen can permeate across the membrane, referred to as crossover. [15] Mixtures of both gases at the electrodes result. At the cathode, oxygen can be catalytically reacted with hydrogen on the platinum surface of the cathodic catalyst. At the anode, hydrogen and oxygen do not react at the iridium oxide catalyst. [15]
Electrolysis of water is the decomposition of water (H 2 O) into oxygen (O 2) and hydrogen (H 2): [2] Water electrolysis ship Hydrogen Challenger. Production of hydrogen from water is energy intensive. Usually, the electricity consumed is more valuable than the hydrogen produced, so this method has not been widely used.
Hydrogen can be purified by passing through a membrane composed of palladium and silver. Permeability of the former to hydrogen was discovered back in the 1860s. [2] An alloy with a ca. 3:1 ratio for Pd:Ag is more structural robust than pure Pd, which is the active component that allows the selective diffusion of H 2 through it.
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