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  2. Chemical reaction - Wikipedia

    en.wikipedia.org/wiki/Chemical_reaction

    Chemical reactions are usually characterized by a chemical change, and they yield one or more products, which usually have properties different from the reactants. Reactions often consist of a sequence of individual sub-steps, the so-called elementary reactions , and the information on the precise course of action is part of the reaction ...

  3. Hess's law - Wikipedia

    en.wikipedia.org/wiki/Hess's_law

    Hess's law states that the change of enthalpy in a chemical reaction is the same regardless of whether the reaction takes place in one step or several steps, provided the initial and final states of the reactants and products are the same. Enthalpy is an extensive property, meaning that its value is proportional to the system size. [4]

  4. Activation energy - Wikipedia

    en.wikipedia.org/wiki/Activation_energy

    The activation energy (E a) of a reaction is measured in kilojoules per mole (kJ/mol) or kilocalories per mole (kcal/mol). [2] Activation energy can be thought of as the magnitude of the potential barrier (sometimes called the energy barrier) separating minima of the potential energy surface pertaining to the initial and final thermodynamic ...

  5. Chemical thermodynamics - Wikipedia

    en.wikipedia.org/wiki/Chemical_thermodynamics

    Chemical thermodynamics is the study of the interrelation of heat and work with chemical reactions or with physical changes of state within the confines of the laws of thermodynamics. Chemical thermodynamics involves not only laboratory measurements of various thermodynamic properties, but also the application of mathematical methods to the ...

  6. Extent of reaction - Wikipedia

    en.wikipedia.org/wiki/Extent_of_reaction

    The extent of reaction represents the amount of progress made towards equilibrium in a chemical reaction. Considering finite changes instead of infinitesimal changes, one can write the equation for the extent of a reaction as = The extent of a reaction is generally defined as zero at the beginning of the reaction. Thus the change of is the ...

  7. Le Chatelier's principle - Wikipedia

    en.wikipedia.org/wiki/Le_Chatelier's_principle

    Le Chatelier–Braun principle analyzes the qualitative behaviour of a thermodynamic system when a particular one of its externally controlled state variables, say , changes by an amount , the 'driving change', causing a change , the 'response of prime interest', in its conjugate state variable , all other externally controlled state variables remaining constant.

  8. Reactivity (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Reactivity_(chemistry)

    In chemistry, reactivity is the impulse for which a chemical substance undergoes a chemical reaction, either by itself or with other materials, with an overall release of energy. Reactivity refers to: the chemical reactions of a single substance, the chemical reactions of two or more substances that interact with each other,

  9. Kinetic isotope effect - Wikipedia

    en.wikipedia.org/wiki/Kinetic_isotope_effect

    In physical organic chemistry, a kinetic isotope effect (KIE) is the change in the reaction rate of a chemical reaction when one of the atoms in the reactants is replaced by one of its isotopes. [3] Formally, it is the ratio of rate constants for the reactions involving the light ( k L ) and the heavy ( k H ) isotopically substituted reactants ...