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This hydrogen peroxide then releases hydrogen peroxide: [(HO) 3 B(OOH)] − + H 2 O ⇌ B(OH) − 4 + H 2 O 2 Several metal hydroperoxide complexes have been characterized by X-ray crystallography, for example: triphenylsilicon and triphenylgermanium hydroperoxides can be obtained by reaction of initial chlorides with excess of hydrogen ...
Others have only peroxide ligands: molybdate reacts in alkaline media with peroxide to form red peroxomolybdate Mo(O 2) 2− 4. [6] The reaction of hydrogen peroxide with aqueous titanium(IV) gives a brightly orange-red colored peroxy complex that is a useful test for titanium as well as hydrogen peroxide. [5]
Especially when in concentrated form, organic peroxides can decompose by self-oxidation, since organic peroxides contain both an oxidizer (the O-O bond) and fuel (C-H and C-C bonds). A "self-accelerating decomposition" occurs when the rate of peroxide decomposition generates heat at a faster rate than it can be dissipated to the environment ...
Acetone peroxide (/ æ s ə ˈ t ə ʊ n p ɛr ˈ ɒ k s aɪ d / ⓘ also called APEX and mother of Satan [3] [4]) is an organic peroxide and a primary explosive. It is produced by the reaction of acetone and hydrogen peroxide to yield a mixture of linear monomer and cyclic dimer, trimer, and tetramer forms. The monomer is dimethyldioxirane.
The peroxide group is marked in blue. R, R 1 and R 2 mark hydrocarbon moieties. The most common peroxide is hydrogen peroxide (H 2 O 2), colloquially known simply as "peroxide". It is marketed as solutions in water at various concentrations. Many organic peroxides are known as well. In addition to hydrogen peroxide, some other major classes of ...
High-test peroxide (HTP) is a highly concentrated (85 to 98%) solution of hydrogen peroxide, with the remainder consisting predominantly of water. In contact with a catalyst, it decomposes into a high-temperature mixture of steam and oxygen, with no remaining liquid water.
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The primary stereoelectronic effect in the Baeyer–Villiger oxidation refers to the necessity of the oxygen-oxygen bond in the peroxide group to be antiperiplanar to the group that migrates. [4] [3] This orientation facilitates optimum overlap of the 𝛔 orbital of the migrating group to the 𝛔* orbital of the peroxide group. [1]