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Phosphate mining in South Carolina declined rapidly in the 1890s, when mining of the higher-grade deposits in central Florida began. The central Florida district has provided the majority of US phosphate ever since. US production of phosphate rock peaked in 1980 at 54.4 million metric tons.
White phosphorus, yellow phosphorus, or simply tetraphosphorus (P 4) is an allotrope of phosphorus. It is a translucent waxy solid that quickly yellows in light (due to its photochemical conversion into red phosphorus ), [ 2 ] and impure white phosphorus is for this reason called yellow phosphorus.
The Bone Valley is a region of central Florida, encompassing portions of present-day Hardee, Hillsborough, Manatee, and Polk counties, in which phosphate is mined for use in the production of agricultural fertilizer. Florida currently contains the largest known deposits of phosphate in the United States.
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Elemental phosphorus exists in two major forms, white phosphorus and red phosphorus, but because it is highly reactive, phosphorus is never found as a free element on Earth. It has an occurrence in the Earth's crust of about 0.1%, generally occurring as phosphate in minerals.
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Phosphorus condenses to a liquid below about 280°C and then solidifies (to the white phosphorus allotrope) below about 44°C (depending on purity). This same essential reaction is still used today (but with mined phosphate ores, coke for carbon, and electric furnaces). Brand's process yielded far less phosphorus than it could have.