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  2. Ethyl acetate - Wikipedia

    en.wikipedia.org/wiki/Ethyl_acetate

    Ethyl acetate (systematically ethyl ethanoate, commonly abbreviated EtOAc, ETAC or EA) is the organic compound with the formula CH 3 CO 2 CH 2 CH 3, simplified to C 4 H 8 O 2.This flammable, colorless liquid has a characteristic sweet smell (similar to pear drops) and is used in glues, nail polish removers, and the decaffeination process of tea and coffee.

  3. Ethyl acetate (data page) - Wikipedia

    en.wikipedia.org/wiki/Ethyl_acetate_(data_page)

    Download as PDF; Printable version; In other projects Wikidata item; ... for Ethyl Acetate/Acetic acid [3] P = 740 mmHg BP Temp. °C % by mole C 4 H 8 O 2; liquid ...

  4. Saponification - Wikipedia

    en.wikipedia.org/wiki/Saponification

    Typically aqueous sodium hydroxide solutions are used. [1] [2] It is an important type of alkaline hydrolysis. When the carboxylate is long chain, its salt is called a soap. The saponification of ethyl acetate gives sodium acetate and ethanol: C 2 H 5 O 2 CCH 3 + NaOH → C 2 H 5 OH + NaO 2 CCH 3

  5. Acetic anhydride - Wikipedia

    en.wikipedia.org/wiki/Acetic_anhydride

    The Tennessee Eastman acetic anhydride process involves the conversion of methyl acetate to methyl iodide and an acetate salt. Carbonylation of the methyl iodide in turn produces acetyl iodide, which reacts with acetate salts or acetic acid to give the product. Rhodium chloride in the presence of lithium iodide is employed as catalysts. Because ...

  6. Acetoacetic ester synthesis - Wikipedia

    en.wikipedia.org/wiki/Acetoacetic_Ester_Synthesis

    Acetoacetic ester synthesis is a chemical reaction where ethyl acetoacetate is alkylated at the α-carbon to both carbonyl groups and then converted into a ketone, or more specifically an α-substituted acetone. This is very similar to malonic ester synthesis. Acetoacetic ester synthesis equation

  7. Ester hydrolysis - Wikipedia

    en.wikipedia.org/wiki/Ester_hydrolysis

    Ester hydrolysis is an organic reaction which hydrolyzes an ester to a carboxylic acid or carboxylate, and an alcohol. It can be performed with acid as catalyst, or with base as reagent. It can be performed with acid as catalyst, or with base as reagent.

  8. Knorr pyrrole synthesis - Wikipedia

    en.wikipedia.org/wiki/Knorr_pyrrole_synthesis

    The original Knorr synthesis employed two equivalents of ethyl acetoacetate, one of which was converted to ethyl 2-oximinoacetoacetate by dissolving it in glacial acetic acid, and slowly adding one equivalent of saturated aqueous sodium nitrite, under external cooling. Zinc dust was then stirred in, reducing the oxime group to the amine. This ...

  9. Taft equation - Wikipedia

    en.wikipedia.org/wiki/Taft_equation

    The hydrolysis of esters can occur through either acid and base catalyzed mechanisms, both of which proceed through a tetrahedral intermediate. In the base catalyzed mechanism the reactant goes from a neutral species to negatively charged intermediate in the rate determining (slow) step , while in the acid catalyzed mechanism a positively ...