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Such charts are particularly important for polymers [4] as they are often not compatible with common chemical reagents; this may even depend on how the polymers have been processed. [5] For example, 3-D printing polymer tools used for chemical experiments must be chosen to ensure chemical compatibility with care. [6]
An advantage to solvent bonding versus other polymer joining methods is that bonding generally occurs below the glass transition temperature of the polymer. [2] [3] Solvent bonding differs from adhesive bonding, because the solvent does not become a permanent addition to the joined substrate. [4] Solvent bonding differs from other plastic ...
The Hildebrand parameter for such non-polar solvents is usually close to the Hansen value. A typical example showing why Hildebrand parameters can be unhelpful is that two solvents, butanol and nitroethane, which have the same Hildebrand parameter, are each incapable of dissolving typical epoxy polymers. Yet a 50:50 mix gives a good solvency ...
Mixture of polymers and solvent on a lattice. Flory–Huggins solution theory is a lattice model of the thermodynamics of polymer solutions which takes account of the great dissimilarity in molecular sizes in adapting the usual expression for the entropy of mixing.
The phase behavior of polymer solutions is an important property involved in the development and design of most polymer-related processes. Partially miscible polymer solutions often exhibit two solubility boundaries, the upper critical solution temperature (UCST) and the LCST, both of which depend on the molar mass and the pressure. At ...
In polymer chemistry, compatibilization is the addition of a substance to an immiscible blend of polymers that will increase their stability. Polymer blends are typically described by coarse, unstable phase morphologies; this results in poor mechanical properties. Compatibilizing the system will make a more stable and better blended phase ...
Solvent vapor annealing (SVA) is a widely used technique for controlling the morphology and ordering of block copolymer (BCP) films. [1] [2] [3] By controlling the block ratio (f = NA/N), spheres, cylinders, gyroids, and lamellae structures can be generated by forming a swollen and mobile layer of thin-film from added solvent vapor to facilitate the self-assembly of the polymer blocks. [4]
A typical vapor phase osmometer consists of: (1) two thermistors, one with a polymer-solvent solution droplet adhered to it and another with a pure solvent droplet adhered to it; (2) a thermostatted chamber with an interior saturated with solvent vapor; (3) a liquid solvent vessel in the chamber; and (4) an electric circuit to measure the bridge output imbalance difference between the two ...
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