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The classical equipartition theorem predicts that the heat capacity ratio (γ) for an ideal gas can be related to the thermally accessible degrees of freedom (f) of a molecule by = +, =. Thus we observe that for a monatomic gas, with 3 translational degrees of freedom per atom: γ = 5 3 = 1.6666 … , {\displaystyle \gamma ={\frac {5}{3}}=1. ...
The ideal gas equation can be rearranged to give an expression for the molar volume of an ideal gas: = = Hence, for a given temperature and pressure, the molar volume is the same for all ideal gases and is based on the gas constant: R = 8.314 462 618 153 24 m 3 ⋅Pa⋅K −1 ⋅mol −1, or about 8.205 736 608 095 96 × 10 −5 m 3 ⋅atm⋅K ...
An important parameter in wet scrubbing systems is the rate of liquid flow. It is common in wet scrubber terminology to express the liquid flow as a function of the gas flow rate that is being treated. This is commonly called the liquid-to-gas ratio (L/G ratio) and uses the units of gallons per 1,000 actual cubic feet or litres per cubic metre ...
Note that the especially high molar values, as for paraffin, gasoline, water and ammonia, result from calculating specific heats in terms of moles of molecules. If specific heat is expressed per mole of atoms for these substances, none of the constant-volume values exceed, to any large extent, the theoretical Dulong–Petit limit of 25 J⋅mol ...
According to Primus Green Energy, the STG+ process converts natural gas into 90+-octane gasoline at approximately 5 US gallons per million British thermal units (65 litres per megawatt-hour). [4] The energy content of gasoline is 120,000 to 125,000 British thermal units per US gallon (9.3 to 9.7 kilowatt-hours per litre), making this process ...
The expansion ratio of a liquefied and cryogenic substance is the volume of a given amount of that substance in liquid form compared to the volume of the same amount of substance in gaseous form, at room temperature and normal atmospheric pressure. [1]
For example, an ideal fuel cell operating at a temperature of 25 °C having gaseous hydrogen and gaseous oxygen as inputs and liquid water as the output could produce a theoretical maximum amount of electrical energy of 237.129 kJ (0.06587 kWh) per gram mol (18.0154 gram) of water produced and would require 48.701 kJ (0.01353 kWh) per gram mol ...
There are a number of correlations for slip ratio. For homogeneous flow, S = 1 (i.e. there is no slip). The Chisholm correlation [2] [3] is: = The Chisholm correlation is based on application of the simple annular flow model and equates the frictional pressure drops in the liquid and the gas phase.