Search results
Results From The WOW.Com Content Network
In coordination chemistry, the ligand cone angle (θ) is a measure of the steric bulk of a ligand in a transition metal coordination complex. It is defined as the solid angle formed with the metal at the vertex of a cone and the outermost edge of the van der Waals spheres of the ligand atoms at the perimeter of the base of the cone.
The bond order of the metal ligand bond can be in part distinguished through the metal ligand bond angle (M−X−R). This bond angle is often referred to as being linear or bent with further discussion concerning the degree to which the angle is bent. For example, an imido ligand in the ionic form has three lone pairs.
The natural bite angle (β n) of diphosphines, obtained using molecular mechanics calculations, is defined as the preferred chelation angle determined only by ligand backbone and not by metal valence angles (Figure 3). [1] Figure 3. Bite angle of a diphosphine ligand bound to rhodium.
The user may choose to replace the inclination angle by its complement, the elevation angle (or altitude angle), measured upward between the reference plane and the radial line—i.e., from the reference plane upward (towards to the positive z-axis) to the radial line. The depression angle is the negative of the elevation angle.
Normal-section azimuth is the angle measured at our viewpoint by a theodolite whose axis is perpendicular to the surface of the spheroid; geodetic azimuth (or geodesic azimuth) is the angle between north and the ellipsoidal geodesic (the shortest path on the surface of the spheroid from our viewpoint to Point 2).
Heading angle σ: angle between north and the horizontal component of the velocity vector, which describes which direction the aircraft is moving relative to cardinal directions. Flight path angle γ: is the angle between horizontal and the velocity vector, which describes whether the aircraft is climbing or descending.
Circular curves are defined by radius (tightness) and deflection angle (extent). The design of a horizontal curve entails the determination of a minimum radius (based on speed limit), curve length, and objects obstructing the view of the driver. [4] Using AASHTO standards, an engineer works to design a road that is safe and comfortable.
Geodetic latitude and geocentric latitude have different definitions. Geodetic latitude is defined as the angle between the equatorial plane and the surface normal at a point on the ellipsoid, whereas geocentric latitude is defined as the angle between the equatorial plane and a radial line connecting the centre of the ellipsoid to a point on the surface (see figure).