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Arsenic is a chemical element with the symbol As and the atomic number 33. It is a metalloid and one of the pnictogens , and therefore shares many properties with its group 15 neighbors phosphorus and antimony .
Arsenic is used as the group 15 element in the III-V semiconductors gallium arsenide, indium arsenide, and aluminium arsenide. [10] The valence electron count of GaAs is the same as a pair of Si atoms, but the band structure is completely different which results in distinct bulk properties. [11]
Arsenic (33 As) has 32 known isotopes and at least 10 isomers. Only one of these isotopes, 75 As, is stable; as such, it is considered a monoisotopic element . The longest-lived radioisotope is 73 As with a half-life of 80 days.
Some arsenic exists in elemental form, but most arsenic is found in the arsenic minerals orpiment, realgar, arsenopyrite, and enargite. [ 14 ] Antimony makes up 0.2 parts per million of the earth's crust, making it the 63rd most abundant element.
Gray, or metallic arsenic, pictured under an argon atmosphere. Gray arsenic, also called grey arsenic or metallic arsenic, is the most stable allotrope of the element at room temperature, and as such is its most common form. [1] This soft, brittle allotrope of arsenic has a steel gray, metallic color, and is a good conductor. [2]
The antileukaemic properties of white arsenic were first reported in 1878. [119] All six of the elements commonly recognised as metalloids have toxic, dietary or medicinal properties. [120] Arsenic and antimony compounds are especially toxic; boron, silicon, and possibly arsenic, are essential trace elements.
In its standard state arsine is a colorless, denser-than-air gas that is slightly soluble in water (2% at 20 °C) [1] and in many organic solvents as well. [citation needed] Arsine itself is odorless, [5] but it oxidizes in air and this creates a slight garlic or fish-like scent when the compound is present above 0.5 ppm. [6]
Realgar (/ r i ˈ æ l ɡ ɑːr,-ɡ ər / ree-AL-gar, -gər), also known as arsenic blende, ruby sulphur or ruby of arsenic, is an arsenic sulfide mineral with the chemical formula α-As 4 S 4. It is a soft, sectile mineral occurring in monoclinic crystals, or in granular, compact, or powdery form, often in association with the related ...