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In organic chemistry, a ketone / ˈ k iː t oʊ n / is an organic compound with the structure R−C(=O)−R', where R and R' can be a variety of carbon-containing substituents. Ketones contain a carbonyl group −C(=O)− (a carbon-oxygen double bond C=O). The simplest ketone is acetone (where R and R' are methyl), with the formula (CH 3) 2 CO ...
The name of the carboxylate anion (R−C(=O)O −) is derived from that of the parent acid by replacing the "–oic acid" ending with "–oate" or "carboxylate." For example, NaC 6 H 5 CO 2, the sodium salt of benzoic acid (C 6 H 5 COOH), is called sodium benzoate.
For example, there are at least two isomers of the linear form of pentanone, a ketone that contains a chain of exactly five carbon atoms. There is an oxygen atom bonded to one of the middle three carbons (if it were bonded to an end carbon, the molecule would be an aldehyde , not a ketone), but it is not clear where it is located.
Download as PDF; Printable version; In other projects Wikimedia Commons; Wikidata item; ... Other carbonyl (C=O) containing classes that are not ketones: Aldehydes ...
The Wieland–Miescher ketone is the Robinson annulation product of 2-methyl-cyclohexane-1,3-dione and methyl vinyl ketone. This compound is used in the syntheses of many steroids possessing important biological properties and can be made enantiopure using proline catalysis. [14] Wieland–Miescher ketone
For example, methanol has been shown to promote aryl migration. [11] [12] As shown below, if the reaction of piperanol (IV) with diazomethane is carried out in the absence of methanol, the ketone obtained though a hydride shift is the major product (V). If methanol is the solvent, an aryl shift occurs to form the aldehyde (VI), which cannot be ...
The product is often an α,β-unsaturated ketone (a conjugated enone). General Knoevenagel layout. In this reaction the carbonyl group is an aldehyde or a ketone. The catalyst is usually a weakly basic amine. The active hydrogen component has the forms: [3]
Cross-coupling reactions are important for the production of pharmaceuticals, [4] examples being montelukast, eletriptan, naproxen, varenicline, and resveratrol. [21] with Suzuki coupling being most widely used. [22] Some polymers and monomers are also prepared in this way. [23]