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Ammonium thiocyanate is used in the manufacture of herbicides, thiourea, and transparent artificial resins; in matches; as a stabilizing agent in photography; in various rustproofing compositions; as an adjuvant in textile dyeing and printing; as a tracer in oil fields; in the separation of hafnium from zirconium (important for the production of hafnium-free zircalloy for use in nuclear fuel ...
[7] [8] [9] Thus the complete absence of thiocyanate or reduced thiocyanate [10] in the human body, (e.g., cystic fibrosis) is damaging to the human host defense system. [11] [12] Thiocyanate is a potent competitive inhibitor of the thyroid sodium-iodide symporter. [13] Iodine is an essential component of thyroxine. Since thiocyanates will ...
In methyl thiocyanate, N≡C and C−S distances are 116 and 176 pm. By contrast, N=C and C=S distances are 117 and 158 pm in isothiocyanates. [7] Typical bond angles for C−S−C are 100°. [3] By contrast C−N=C in aryl isothiocyanates is 165°. Again, the thiocyanate isomers are quite different with C−S−C angle near 100°.
Thiourea (/ ˌ θ aɪ. oʊ j ʊəˈr iː. ə,-ˈ jʊər i-/) [2] [3] [4] is an organosulfur compound with the formula SC(NH 2) 2 and the structure H 2 N−C(=S)−NH 2.It is structurally similar to urea (H 2 N−C(=O)−NH 2), except that the oxygen atom is replaced by a sulfur atom (as implied by the thio-prefix); however, the properties of urea and thiourea differ significantly.
Thiocyanic acid is a chemical compound with the formula H S C N and structure H−S−C≡N, which exists as a tautomer with isothiocyanic acid (H−N=C=S). [8] The isothiocyanic acid tautomer tends to dominate with the compound being about 95% isothiocyanic acid in the vapor phase. [9] Tautomerism between thiocyanic acid (left) and ...
Allyl thiocyanate isomerizes to the isothiocyanate: [4] CH 2 =CHCH 2 SCN → CH 2 =CHCH 2 NCS. Isothiocyanates can be prepared by treating organic dithiocarbamate salts with lead nitrate or tosyl chloride. [5] [6] Synthesis of phenyl isothiocyanate. Isothiocyanates may also be accessed by the fragmentation reactions of 1,4,2-oxathiazoles. [7]
A chaotropic agent is a molecule in water solution that can disrupt the hydrogen bonding network between water molecules (i.e. exerts chaotropic activity).This has an effect on the stability of the native state of other molecules in the solution, mainly macromolecules (proteins, nucleic acids) by weakening the hydrophobic effect.
In chemistry, chemical stability is the thermodynamic stability of a chemical system, in particular a chemical compound or a polymer. [ 1 ] Chemical stability may also refer to the shelf-life of a particular chemical compound; that is the duration of time before it begins to degrade in response to environmental factors.