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The pressure exerted by a column of liquid of height h and density ρ is given by the hydrostatic pressure equation p = ρgh, where g is the gravitational acceleration. Fluid density and local gravity can vary from one reading to another depending on local factors, so the height of a fluid column does not define pressure precisely.
In a liquid solution the activity coefficient of a given ion (e.g. Ca 2+) isn't measurable because it is experimentally impossible to independently measure the electrochemical potential of an ion in solution. (One cannot add cations without putting in anions at the same time). Therefore, one introduces the notions of mean ionic activity a ν ± ...
A liquid is a nearly incompressible fluid that conforms to the shape of its container but retains a nearly constant volume independent of pressure. It is one of the four fundamental states of matter (the others being solid, gas, and plasma), and is the only state with a definite volume but no fixed shape.
Raoult's law (/ ˈ r ɑː uː l z / law) is a relation of physical chemistry, with implications in thermodynamics.Proposed by French chemist François-Marie Raoult in 1887, [1] [2] it states that the partial pressure of each component of an ideal mixture of liquids is equal to the vapor pressure of the pure component (liquid or solid) multiplied by its mole fraction in the mixture.
This is true whenever the solid phase is denser than the liquid phase. [6] The greater the pressure on a given substance, the closer together the molecules of the substance are brought to each other, which increases the effect of the substance's intermolecular forces. Thus, the substance requires a higher temperature for its molecules to have ...
The International System of Units (SI) recognizes pressure as a derived unit with the dimension of force per area and designates the pascal (Pa) as its standard unit. [1] One pascal is one newton per square meter (N·m −2 or kg·m −1 ·s −2). Experimental measurement of vapor pressure is a simple procedure for common pressures between 1 ...
In physics and chemistry, an equation of state is a thermodynamic equation relating state variables, which describe the state of matter under a given set of physical conditions, such as pressure, volume, temperature, or internal energy. [1] [2] Most modern equations of state are formulated in the Helmholtz free energy.
The coefficients of Antoine's equation are normally given in mmHg—even today where the SI is recommended and pascals are preferred. The usage of the pre-SI units has only historic reasons and originates directly from Antoine's original publication. It is however easy to convert the parameters to different pressure and temperature units.