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An infrared spectroscopy correlation table (or table of infrared absorption frequencies) is a list of absorption peaks and frequencies, typically reported in wavenumber, for common types of molecular bonds and functional groups.
The vibrational frequencies of most molecules correspond to the frequencies of infrared light. Typically, the technique is used to study organic compounds using light radiation from the mid-infrared, 4,000–400 cm −1. A spectrum of all the frequencies of absorption in a sample is recorded.
The method or technique of infrared spectroscopy is conducted with an instrument called an infrared spectrometer (or spectrophotometer) which produces an infrared spectrum. An IR spectrum can be visualized in a graph of infrared light absorbance (or transmittance ) on the vertical axis vs. frequency , wavenumber or wavelength on the horizontal ...
A diagram of the electromagnetic spectrum, showing various properties across the range of frequencies and wavelengths. The electromagnetic spectrum is the full range of electromagnetic radiation, organized by frequency or wavelength. The spectrum is divided into separate bands, with different names for the electromagnetic waves within each band.
Far infrared (FIR) or long wave refers to a specific range within the infrared spectrum of electromagnetic radiation. It encompasses radiation with wavelengths ranging from 15 μm (micrometers) to 1 mm, which corresponds to a frequency range of approximately 20 THz to 300 GHz. This places far infrared radiation within the CIE IR-B and IR-C ...
A molecular vibration is a periodic motion of the atoms of a molecule relative to each other, such that the center of mass of the molecule remains unchanged. The typical vibrational frequencies range from less than 10 13 Hz to approximately 10 14 Hz, corresponding to wavenumbers of approximately 300 to 3000 cm −1 and wavelengths of approximately 30 to 3 μm.
Two-dimensional infrared spectroscopy (2D IR) is a nonlinear infrared spectroscopy technique that has the ability to correlate vibrational modes in condensed-phase systems. This technique provides information beyond linear infrared spectra, by spreading the vibrational information along multiple axes, yielding a frequency correlation spectrum.
AFM-IR enables nanoscale infrared spectroscopy, [52] i.e. the ability to obtain infrared absorption spectra from nanoscale regions of a sample. Chemical compositional mapping AFM-IR can also be used to perform chemical imaging or compositional mapping with spatial resolution down to ~10-20 nm, [18] limited only by the radius of the AFM tip. In ...