Search results
Results From The WOW.Com Content Network
A phase diagram in physical chemistry, engineering, mineralogy, and materials science is a type of chart used to show conditions (pressure, temperature, etc.) at which thermodynamically distinct phases (such as solid, liquid or gaseous states) occur and coexist at equilibrium.
The solidus is the locus of temperatures (a curve on a phase diagram) below which a given substance is completely solid (crystallized). The solidus temperature specifies the temperature below which a material is completely solid, [2] and the minimum temperature at which a melt can co-exist with crystals in thermodynamic equilibrium.
In chemistry, the lever rule is a formula used to determine the mole fraction (x i) or the mass fraction (w i) of each phase of a binary equilibrium phase diagram.It can be used to determine the fraction of liquid and solid phases for a given binary composition and temperature that is between the liquidus and solidus line.
Phase transitions commonly refer to when a substance transforms between one of the four states of matter to another. At the phase transition point for a substance, for instance the boiling point, the two phases involved - liquid and vapor, have identical free energies and therefore are equally likely to exist.
However, only solid→liquid and liquid→solid phase changes are practical for PCMs. Although liquid–gas transitions have a higher heat of transformation than solid–liquid transitions, liquid→gas phase changes are impractical for thermal storage because large volumes or high pressures are required to store the materials in their gas phase.
When the phase change occurs, there is a "thermal arrest"; that is, the temperature stays constant. This is because the matter has more internal energy as a liquid or gas than in the state that it is cooling to. The amount of energy required for a phase change is known as latent heat. The "cooling rate" is the slope of the cooling curve at any ...
As such, condensation can be associated with phase transition, and the macroscopic occupation of the state is the order parameter. Bose–Einstein condensate was first predicted, generally, in 1924–1925 by Albert Einstein , [ 2 ] crediting a pioneering paper by Satyendra Nath Bose on the new field now known as quantum statistics . [ 3 ]
After the transition is complete, adding more heat increases the temperature. In other words, the enthalpy of a substance changes isothermally as it undergoes a physical change. The enthalpy change resulting from a phase transition is designated ΔH. There are four types of enthalpy changes resulting from a phase transition. To wit: