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The major side-product is the related compound 1,1,2-trichloroethane, from which the 1,1,1-trichloroethane can be separated by distillation. A somewhat smaller amount of 1,1,1-trichloroethane is produced from the reaction of 1,1-dichloroethene and hydrogen chloride in the presence of an iron(III) chloride catalyst: CH 2 =CCl 2 + HCl → CH 3 CCl 3
The demand for TCE as a degreaser began to decline in the 1950s in favor of the less toxic 1,1,1-trichloroethane. However, 1,1,1-trichloroethane production has been phased out in most of the world under the terms of the Montreal Protocol due to its contribution to the ozone depletion. As a result, trichloroethylene has experienced some ...
Organochlorine chemistry is concerned with the properties of organochlorine compounds, or organochlorides, organic compounds that contain one or more carbon–chlorine bonds. [1] The chloroalkane class (alkanes with one or more hydrogens substituted by chlorine) includes common examples. The wide structural variety and divergent chemical ...
In the laboratory it is occasionally used as a source of chlorine, with elimination of ethene and chloride. Via several steps, 1,2-dichloroethane is a precursor to 1,1,1-trichloroethane. Historically, before leaded petrol was phased out, chloroethanes were used as an additive in petrol to prevent lead buildup in engines. [10]
[3] [4] Historically 1,1,1-Trichloroethane was used, sometimes together with Tetrachloroethylene. It was phased out because of its ozone-depleting nature. [5] Non-chlorinated brake cleaners use hydrocarbons as a main component; it will either be a low-boiling aliphatic compound or higher-boiling hydrocarbon mixture.
1,1,2-Trichloro-1,2,2-trifluoroethane, also called trichlorotrifluoroethane (often abbreviated as TCTFE) or CFC-113, is a chlorofluorocarbon. It has the formula Cl 2 FC−CClF 2 . This colorless, volatile liquid is a versatile solvent.
1,1,2-Trichloroethane, vinyl trichloride or 1,1,2-TCA, is an organochloride solvent with the molecular formula C 2 H 3 Cl 3 and the structural formula CH 2 Cl—CHCl 2. It is a colourless, sweet-smelling liquid that does not dissolve in water, but is soluble in most organic solvents. It is an isomer of 1,1,1-trichloroethane, and a byproduct of ...
Tetrachloroethylene, also known as perchloroethylene [a] or under the systematic name tetrachloroethene, and abbreviations such as perc (or PERC), and PCE, is a chlorocarbon with the formula Cl 2 C=CCl 2. It is a non-flammable, stable, colorless and heavy liquid widely used for dry cleaning of fabrics.