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The method of image charges (also known as the method of images and method of mirror charges) is a basic problem-solving tool in electrostatics.The name originates from the replacement of certain elements in the original layout with fictitious charges, which replicates the boundary conditions of the problem (see Dirichlet boundary conditions or Neumann boundary conditions).
The Poisson–Boltzmann equation can be applied to biomolecular systems. One example is the binding of electrolytes to biomolecules in a solution. This process is dependent upon the electrostatic field generated by the molecule, the electrostatic potential on the surface of the molecule, as well as the electrostatic free energy. [13]
The Taft equation is a linear free energy relationship (LFER) used in physical organic chemistry in the study of reaction mechanisms and in the development of quantitative structure–activity relationships for organic compounds. It was developed by Robert W. Taft in 1952 [2] [3] [4] as a modification to the Hammett equation. [5]
The Thomson problem also plays a role in the study of other physical models including multi-electron bubbles and the surface ordering of liquid metal drops confined in Paul traps. The generalized Thomson problem arises, for example, in determining arrangements of protein subunits that comprise the shells of spherical viruses. The "particles" in ...
Faraday's ice pail experiment is a simple electrostatics experiment performed in 1843 by British scientist Michael Faraday [1] [2] that demonstrates the effect of electrostatic induction on a conducting container. For a container, Faraday used a metal pail made to hold ice, which gave the experiment its name. [3]
Protein folding problem: Is it possible to predict the secondary, tertiary and quaternary structure of a polypeptide sequence based solely on the sequence and environmental information? Inverse protein-folding problem: Is it possible to design a polypeptide sequence which will adopt a given structure under certain environmental conditions?
Φ is the local electrostatic potential in V. In the special case of an uncharged atom, z i = 0, and so μ i = μ i . Electrochemical potential is important in biological processes that involve molecular diffusion across membranes, in electroanalytical chemistry, and industrial applications such as batteries and fuel cells.
In classical electrostatics, the electrostatic field is a vector quantity expressed as the gradient of the electrostatic potential, which is a scalar quantity denoted by V or occasionally φ, [1] equal to the electric potential energy of any charged particle at any location (measured in joules) divided by the charge of that particle (measured ...