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Depending on the environmental conditions present at the time of their formation, concretions can be created by either concentric or pervasive growth. [11] [12] In concentric growth, the concretion grows as successive layers of mineral precipitate around a central core. This process results in roughly spherical concretions that grow with time.
Similar to the marine nodules, concretion layers are defined based on iron and manganese content as well as their combination. [2] High iron content nodules appear a red or brown color, while high manganese content appears black or grey. [2] The dominant metal oxide is related to the elements enriched in the nodule.
Ferricrete is a hard, erosion-resistant layer of sedimentary rock, usually conglomerate or breccia, that has been cemented into a duricrust by iron oxides. The iron oxide cements are derived from the oxidation of percolating solutions of iron salts. [1]
The iron forming these concretions came from the breakdown of iron-bearing silicate minerals by weathering to form iron oxide coatings on other grains. During later diagenesis of the Navajo Sandstone while deeply buried, reducing fluids , likely hydrocarbons , dissolved these coatings.
The above classification scheme is the most commonly used and accepted, though sometimes an older system is used which divides iron-rich sedimentary rocks into three categories: bog iron deposits, ironstones, and iron formations. A bog-iron deposit is iron that formed in a bog or swamp through the process of oxidation.
Iron is stored in many organisms in the form of ferritin, which is a ferrous oxide encased in a solubilizing protein sheath. [ 10 ] Species of bacteria , including Shewanella oneidensis , Geobacter sulfurreducens and Geobacter metallireducens , use iron oxides as terminal electron acceptors .
Although channel iron deposits are typically low-grade at 53% to 57% Fe in-situ, they are composed of goethite-limonite which are hydrated iron oxide species. Ore typically contains around 8% to 12% water, and <5% SiO 2, and <3% Al 2 O 3. The hydrous iron oxides can be calcined, and the CID ore on a volatile-free basis is around 63% Fe or more.
Iron(III) oxide is a product of the oxidation of iron. It can be prepared in the laboratory by electrolyzing a solution of sodium bicarbonate, an inert electrolyte, with an iron anode: 4 Fe + 3 O 2 + 2 H 2 O → 4 FeO(OH) The resulting hydrated iron(III) oxide, written here as FeO(OH), dehydrates around 200 °C. [18] [19] 2 FeO(OH) → Fe 2 O 3 ...