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For a fully oriented molecule, the dipolar coupling for an 1 H-15 N amide group would be over 20 kHz, and a pair of protons separated by 5 Å would have up to ~1 kHz coupling. However the degree of alignment achieved by applying magnetic field is so low that the largest 1 H-15 N or 1 H-13 C dipolar couplings are <5 Hz. [19]
Magnetic dipole–dipole interaction, also called dipolar coupling, refers to the direct interaction between two magnetic dipoles. Roughly speaking, the magnetic field of a dipole goes as the inverse cube of the distance, and the force of its magnetic field on another dipole goes as the first derivative of the magnetic field. It follows that ...
Solid-state 900 MHz (21.1 T [1]) NMR spectrometer at the Canadian National Ultrahigh-field NMR Facility for Solids. Solid-state nuclear magnetic resonance (ssNMR) is a spectroscopy technique used to characterize atomic-level structure and dynamics in solid materials. ssNMR spectra are broader due to nuclear spin interactions which can be categorized as dipolar coupling, chemical shielding ...
In 1958 a study of the yielding of soil based on some Cambridge data of the simple shear apparatus tests, and on much more extensive data of triaxial tests at Imperial College London from research led by Professor Sir Alec Skempton at Imperial College, led to the publication of the critical state concept (Roscoe, Schofield & Wroth 1958).
The jet erosion test (JET), or jet index test, is a method used in geotechnical engineering to quantify the resistance of a soil to erosion. The test can be applied in-situ after preparing a field site, or it can be applied in a laboratory on either an intact or a remolded soil sample .
The Universal Soil Loss Equation (USLE) is a widely used mathematical model that describes soil erosion processes. [1]Erosion models play critical roles in soil and water resource conservation and nonpoint source pollution assessments, including: sediment load assessment and inventory, conservation planning and design for sediment control, and for the advancement of scientific understanding.
The Water Erosion Prediction Project (WEPP) model is a physically based erosion simulation model built on the fundamentals of hydrology, plant science, hydraulics, and erosion mechanics. [ 1 ] [ 2 ] The model was developed by an interagency team of scientists to replace the Universal Soil Loss Equation (USLE) and has been widely used in the ...
The "feet" of the lineshape correspond to the situation when the principal axis of the coupling interaction is parallel to the magnetic field which is much less statistically relevant. Pake was the first to describe this lineshape and used it to extract the proton-proton distance from his experiments on a single crystal and powdered hydrates of ...