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In the physical sciences, the wavenumber (or wave number), also known as repetency, [1] is the spatial frequency of a wave, measured in cycles per unit distance (ordinary wavenumber) or radians per unit distance (angular wavenumber). [2][3][4] It is analogous to temporal frequency, which is defined as the number of wave cycles per unit time ...
The Balmer series, or Balmer lines in atomic physics, is one of a set of six named series describing the spectral line emissions of the hydrogen atom. The Balmer series is calculated using the Balmer formula, an empirical equation discovered by Johann Balmer in 1885. The visible spectrum of light from hydrogen displays four wavelengths, 410 nm ...
In 1890, Rydberg proposed on a formula describing the relation between the wavelengths in spectral lines of alkali metals. [2]: v1:376 He noticed that lines came in series and he found that he could simplify his calculations using the wavenumber (the number of waves occupying the unit length, equal to 1/λ, the inverse of the wavelength) as his unit of measurement.
In physics and mathematics, wavelength or spatial period of a wave or periodic function is the distance over which the wave's shape repeats. [1][2] In other words, it is the distance between consecutive corresponding points of the same phase on the wave, such as two adjacent crests, troughs, or zero crossings.
Formally, the wavelength version of Wien's displacement law states that the spectral radiance of black-body radiation per unit wavelength, peaks at the wavelength given by: where T is the absolute temperature and b is a constant of proportionality called Wien's displacement constant, equal to 2.897771955...×10−3m⋅K, 1 2 or b ≈ 2898 μm ⋅K.
Lyman series. In physics and chemistry, the Lyman series is a hydrogen spectral series of transitions and resulting ultraviolet emission lines of the hydrogen atom as an electron goes from n ≥ 2 to n = 1 (where n is the principal quantum number), the lowest energy level of the electron (groundstate). The transitions are named sequentially by ...
Rydberg constant. In spectroscopy, the Rydberg constant, symbol for heavy atoms or for hydrogen, named after the Swedish physicist Johannes Rydberg, is a physical constant relating to the electromagnetic spectra of an atom. The constant first arose as an empirical fitting parameter in the Rydberg formula for the hydrogen spectral series, but ...
A molecular vibration is a periodic motion of the atoms of a molecule relative to each other, such that the center of mass of the molecule remains unchanged. The typical vibrational frequencies range from less than 10 13 Hz to approximately 10 14 Hz, corresponding to wavenumbers of approximately 300 to 3000 cm −1 and wavelengths of approximately 30 to 3 μm.