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Silver acetate is a reagent for direct ortho-arylation (to install two adjacent substituents on an aromatic ring) of benzylamines and N-methylbenzylamines.The reaction is palladium-catalyzed and requires a slight excess of silver acetate. [7]
Mercury(II) acetate, also known as mercuric acetate is a chemical compound, the mercury(II) salt of acetic acid, with the formula Hg(O 2 CCH 3) 2.Commonly abbreviated Hg(OAc) 2, this compound is employed as a reagent to generate organomercury compounds from unsaturated organic precursors.
The structure of the acetoxy group blue. In organic chemistry, the acetoxy group (abbr. AcO or OAc; IUPAC name: acetyloxy [1]), is a functional group with the formula −OCOCH 3 and the structure −O−C(=O)−CH 3. As the -oxy suffix implies, it differs from the acetyl group (−C(=O)−CH 3) by the presence of an additional oxygen atom.
The Woodward cis-hydroxylation (also known as the Woodward reaction) is the chemical reaction of alkenes with iodine and silver acetate in wet acetic acid to form cis-diols. [1] [2] (conversion of olefin into cis-diol)
Structure. The anhydrous material and dihydrate Mn(CH 3 CO 2) 2 ·2H 2 O are coordination polymers. The dihydrate has been characterized by X-ray crystallography.
It has a trimeric structure, consisting of an equilateral triangle of Pd atoms each pair of which is bridged with two acetate groups in a butterfly conformation. [3] [4] Palladium(II) acetate can also be prepared as a pale pink form. According to X-ray powder diffraction, this form is polymeric. [5]
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structure of the cation called basic iron acetate as determined from X-ray crystallography [4] Basic iron acetate forms on treating aqueous solutions of iron(III) sources with acetate salts. It is slowly soluble in water and poorly soluble in acetic acid. [5] A typical precursor is freshly precipitated iron oxide/hydroxide, which is halide-free ...