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This is an accepted version of this page This is the latest accepted revision, reviewed on 4 February 2025. This article is about the chemical element. For other uses, see Iodine (disambiguation). Chemical element with atomic number 53 (I) Iodine, 53 I Iodine Pronunciation / ˈ aɪ ə d aɪ n, - d ɪ n, - d iː n / (EYE -ə-dyne, -din, -deen) Appearance lustrous metallic gray solid ...
Iodine trichloride, which exists in the solid state as the planar dimer I 2 Cl 6, is a bright yellow solid, synthesised by reacting iodine with liquid chlorine at −80 °C; caution is necessary during purification because it easily dissociates to iodine monochloride and chlorine and hence can act as a strong chlorinating agent.
Compounds with iodine in formal oxidation state −1 are called iodides. In everyday life, iodide is most commonly encountered as a component of iodized salt , which many governments mandate. Worldwide, iodine deficiency affects two billion people and is the leading preventable cause of intellectual disability .
Iodate is one of several oxyanions of iodine, and has an oxidation number of +5. It participates in several redox reactions, such as the iodine clock reaction. Iodate shows no tendency to disproportionate to periodate and iodide, in contrast to the situation for chlorate. Iodate is reduced by sulfite: [1] 6HSO − 3 + 2IO − 3 → 2I − ...
Tetraiodine nonoxide is a light yellow solid that can easily hydrolyze. It decomposes above 75 °C: [2] 4 I 4 O 9 → 6 I 2 O 5 + 2 I 2 + 3 O 2. Like diiodine tetroxide, tetraiodine nonoxide contains both I(III) and I(V), and disproportionate to iodate and iodide under alkaline conditions: [2] 3 I 4 O 9 + 12 HO − → I − + 11 IO − 3 + 6 H 2 O
Partition coefficients can also be defined when one of the phases is solid, for instance, when one phase is a molten metal and the second is a solid metal, [6] or when both phases are solids. [7] The partitioning of a substance into a solid results in a solid solution .
Silver iodide is an inorganic compound with the formula Ag I. The compound is a bright yellow solid, but samples almost always contain impurities of metallic silver that give a grey colouration. The silver contamination arises because some samples of AgI can be highly photosensitive. This property is exploited in silver-based photography.
The following exergonic equilibrium gives rise to the triiodide ion: . I 2 + I − ⇌ I − 3. In this reaction, iodide is viewed as a Lewis base, and the iodine is a Lewis acid.The process is analogous to the reaction of S 8 with sodium sulfide (which forms polysulfides) except that the higher polyiodides have branched structures.