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Alcoholic fermentation converts one mole of glucose into two moles of ethanol and two moles of carbon dioxide, producing two moles of ATP in the process. C 6 H 12 O 6 + 2 ADP + 2 P i → 2 C 2 H 5 OH + 2 CO 2 + 2 ATP. Sucrose is a sugar composed of a glucose linked to a fructose.
Alcohol oxidation is a collection of oxidation reactions in organic chemistry that convert alcohols to aldehydes, ketones, carboxylic acids, and esters. The reaction mainly applies to primary and secondary alcohols. Secondary alcohols form ketones, while primary alcohols form aldehydes or carboxylic acids. [1] A variety of oxidants can be used.
The reaction is often carried out without a solvent (particularly when a large reagent excess of the alcohol reagent is used) or in a non-polar solvent (e.g. toluene, hexane) that can facilitate Dean–Stark distillation to remove the water byproduct. [4] Typical reaction times vary from 1–10 hours at temperatures of 60–110 °C.
Fischer glycosidation (or Fischer glycosylation) refers to the formation of a glycoside by the reaction of an aldose or ketose with an alcohol in the presence of an acid catalyst. The reaction is named after the German chemist, Emil Fischer, winner of the Nobel Prize in chemistry, 1902, who developed this method between 1893 and 1895. [1] [2] [3]
Ethanol is not used industrially as a precursor to ethyl halides, but the reactions are illustrative. Ethanol reacts with hydrogen halides to produce ethyl halides such as ethyl chloride and ethyl bromide via an S N 2 reaction: CH 3 CH 2 OH + HCl → CH 3 CH 2 Cl + H 2 O. HCl requires a catalyst such as zinc chloride. [116]
The mixed acid fermentation pathway in E. coli. [1] [2] End products are highlighted in blue.In biochemistry, mixed acid fermentation is the metabolic process by which a six-carbon sugar (e.g. glucose, C 6 H 12 O 6) is converted into a complex and variable mixture of acids.
The reaction usually requires a catalyst, such as concentrated sulfuric acid: R−OH + R'−CO 2 H → R'−CO 2 R + H 2 O. Other types of ester are prepared in a similar manner−for example, tosyl (tosylate) esters are made by reaction of the alcohol with 4-toluenesulfonyl chloride in pyridine.
The conversion of ethanol to ethylene is a fundamental example: [3] [4] CH 3 CH 2 OH → H 2 C=CH 2 + H 2 O. The reaction is accelerated by acid catalysts such as sulfuric acid and certain zeolites. These reactions often proceed via carbocation intermediates as shown for the dehydration of cyclohexanol. [5] Some alcohols are prone to dehydration.