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The RFQ trap is used convert the radioactive ion beam delivered by the ISOLDE facility into low-energy ion pulses, before it is injected into the MR-ToF mass spectrometer. [5] It does this by electrostatically decelerating the ions and then passing them through a buffer-gas -filled environment. [ 6 ]
An ion trap, used for precision measurements of radium ions, inside a vacuum chamber. View ports surrounding the chamber allow laser light to be directed into the trap. An ion trap is a combination of electric and/or magnetic fields used to capture charged particles — known as ions — often in a system isolated from an external environment.
In the reflection, the higher energy ion (red) takes a longer path but arrives at the detector at the same time as the lower energy ion (blue) of the same mass. The idea of improving mass resolution in TOF MS by implementing the reflection of ions from a region with retarding electric field (the ion mirror) has been first proposed by Russian ...
A TOF mass spectrometer can also have a low-duty cycle when coupled with a continuous ion source. Combining an ion trap with a TOF mass analyzer can improve the duty cycle. Both 3D and linear traps have been combined with TOF mass analyzers. A trap can also add MSn capabilities to the system. [1]
In experimental physics, a quadrupole ion trap or paul trap is a type of ion trap that uses dynamic electric fields to trap charged particles. They are also called radio frequency (RF) traps or Paul traps in honor of Wolfgang Paul , who invented the device [ 1 ] [ 2 ] and shared the Nobel Prize in Physics in 1989 for this work. [ 3 ]
A sector instrument can be combined with a collision quadrupole and quadrupole mass analyzer to form a hybrid instrument. [1] A BEqQ configuration with a magnetic sector (B), electric sector (E), collision quadrupole (q) and m/z selection quadrupole (Q) have been constructed [2] [3] and an instrument with two electric sectors (BEEQ) has been described.
Ion trajectories in an Orbitrap mass spectrometer. In mass spectrometry, Orbitrap is an ion trap mass analyzer consisting of an outer barrel-like electrode and a coaxial inner spindle-like electrode that traps ions in an orbital motion around the spindle.
The sample ion current (I +) is the measure of the ionization rate. This can be enhanced by manipulation of the ion extraction efficiency (β), the total ionizing cross section (Q i), the effective ionizing path length (L), the concentration of the sample molecules([N]) and the ionizing current (I e). The equation can be shown as follows: