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These tables list values of molar ionization energies, measured in kJ⋅mol −1. This is the energy per mole necessary to remove electrons from gaseous atoms or atomic ions. The first molar ionization energy applies to the neutral atoms.
Values from CRC are ionization energies given in the unit eV; other values are molar ionization energies given in the unit kJ/mol.The first of these quantities is used in atomic physics, the second in chemistry, but both refer to the same basic property of the element.
One mole of particles given 1 eV of energy each has approximately 96.5 kJ of energy – this corresponds to the Faraday constant (F ≈ 96 485 C⋅mol −1), where the energy in joules of n moles of particles each with energy E eV is equal to E·F·n.
List of orders of magnitude for energy; Factor (joules) SI prefix Value Item 10 −34: 6.626 × 10 −34 J: Energy of a photon with a frequency of 1 hertz. [1]8 × 10 −34 J: Average kinetic energy of translational motion of a molecule at the lowest temperature reached (38 picokelvin [2] as of 2021)
In chemistry, it is expressed as the energy to ionize a mole of atoms or molecules, usually as kilojoules per mole (kJ/mol) or kilocalories per mole (kcal/mol). [3] Comparison of ionization energies of atoms in the periodic table reveals two periodic trends which follow the rules of Coulombic attraction: [4]
Electron affinity can be defined in two equivalent ways. First, as the energy that is released by adding an electron to an isolated gaseous atom. The second (reverse) definition is that electron affinity is the energy required to remove an electron from a singly charged gaseous negative ion.
Boltzmann constant: The Boltzmann constant, k, is one of seven fixed constants defining the International System of Units, the SI, with k = 1.380 649 x 10 −23 J K −1.The Boltzmann constant is a proportionality constant between the quantities temperature (with unit kelvin) and energy (with unit joule).
It is also an SI derived unit of molar thermodynamic energy defined as the energy equal to one joule in one mole of substance. [1] [2] For example, the Gibbs free energy of a compound in the area of thermochemistry is often quantified in units of kilojoules per mole (symbol: kJ·mol −1 or kJ/mol), with 1 kilojoule = 1000 joules. [3] Physical ...