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The isotopes 284 Nh, 285 Nh, and 286 Nh have half-lives long enough for chemical investigation. [118] From 2010 to 2012, some preliminary chemical experiments were performed at the JINR to determine the volatility of nihonium. The isotope 284 Nh was investigated, made as the daughter of 288 Mc produced in the 243 Am+ 48 Ca reaction.
In organic chemistry, neighbouring group participation (NGP, also known as anchimeric assistance) has been defined by the International Union of Pure and Applied Chemistry (IUPAC) as the interaction of a reaction centre with a lone pair of electrons in an atom or the electrons present in a sigma or pi bond contained within the parent molecule but not conjugated with the reaction centre.
Pauling invoked the principle of electroneutrality in a 1952 paper to suggest that pi bonding is present, for example, in molecules with 4 Si-O bonds. [8] The oxygen atoms in such molecules would form polar covalent bonds with the silicon atom because their electronegativity (electron withdrawing power) was higher than that of silicon.
A plastic ball-and-stick model of proline. In chemistry, the ball-and-stick model is a molecular model of a chemical substance which displays both the three-dimensional position of the atoms and the bonds between them. [1] The atoms are typically represented by spheres, connected by rods which represent the bonds.
In chemistry, π-effects or π-interactions are a type of non-covalent interaction that involves π systems.Just like in an electrostatic interaction where a region of negative charge interacts with a positive charge, the electron-rich π system can interact with a metal (cationic or neutral), an anion, another molecule and even another π system. [1]
The isoelectric point (pI, pH(I), IEP), is the pH at which a molecule carries no net electrical charge or is electrically neutral in the statistical mean. The standard nomenclature to represent the isoelectric point is pH(I). [1] However, pI is also used. [2] For brevity, this article uses pI.
Piperidine is an organic compound with the molecular formula (CH 2) 5 NH. This heterocyclic amine consists of a six-membered ring containing five methylene bridges (–CH 2 –) and one amine bridge (–NH–). It is a colorless liquid with an odor described as objectionable, typical of amines. [6]
Interstellar NH was identified in the diffuse clouds toward ζ Persei and HD 27778 from high-resolution high-signal-to-noise spectra of the NH A 3 Π→X 3 Σ (0,0) absorption band near 3358 Å. [7] A temperature of about 30 K (−243 °C) favored an efficient production of CN from NH within the diffuse cloud.