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For an isentropic flow of a perfect gas, several relations can be derived to define the pressure, density and temperature along a streamline. Note that energy can be exchanged with the flow in an isentropic transformation, as long as it doesn't happen as heat exchange. An example of such an exchange would be an isentropic expansion or ...
Note that before and after the shock the isentropic relations are valid and connect static and total quantities. That means, p t o t a l ≠ p s t a t i c + p d y n a m i c {\displaystyle p_{total}\neq p_{static}+p_{dynamic}} (comes from Bernoulli, assumes incompressible flow) because the flow is for Mach numbers greater than unity always ...
See relations between specific heats for the derivation of the thermodynamic relations between the heat capacities. The above definition is the approach used to develop rigorous expressions from equations of state (such as Peng–Robinson ), which match experimental values so closely that there is little need to develop a database of ratios or ...
Clausius–Clapeyron relation; Departure functions; Duhem–Margules equation; Ehrenfest equations; Gibbs–Helmholtz equation; Phase rule; Kopp's law; Noro–Frenkel law of corresponding states; Onsager reciprocal relations; Stefan number; Thermodynamics; Timeline of thermodynamics; Triple product rule; Exact differential
When the change in flow variables is small and gradual, isentropic flows occur. The generation of sound waves is an isentropic process. A supersonic flow that is turned while there is an increase in flow area is also isentropic. Since there is an increase in area, therefore we call this an isentropic expansion.
The structure of Maxwell relations is a statement of equality among the second derivatives for continuous functions. It follows directly from the fact that the order of differentiation of an analytic function of two variables is irrelevant (Schwarz theorem).
For isentropic compression, ν ( M 2 ) = ν ( M 1 ) − θ {\displaystyle \nu (M_{2})=\nu (M_{1})-\theta \,} where, θ {\displaystyle \theta } is the absolute value of the angle through which the flow turns, M {\displaystyle M} is the flow Mach number and the suffixes "1" and "2" denote the initial and final conditions respectively.
The difference relation allows one to obtain the heat capacity for solids at constant volume which is not readily measured in terms of quantities that are more easily measured. The ratio relation allows one to express the isentropic compressibility in terms of the heat capacity ratio.