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In the simplest case, the cation is a metal atom and the anion is a nonmetal atom, but these ions can be more complex, e.g. polyatomic ions like NH + 4 or SO 2− 4. In simpler words, an ionic bond results from the transfer of electrons from a metal to a non-metal to obtain a full valence shell for both atoms.
Oxidative additions of nonpolar substrates such as hydrogen and hydrocarbons appear to proceed via concerted pathways. Such substrates lack π-bonds, consequently a three-centered σ complex is invoked, followed by intramolecular ligand bond cleavage of the ligand (probably by donation of electron pair into the sigma* orbital of the inter ligand bond) to form the oxidized complex.
If it is the result of a reaction between a strong base and a weak acid, the result is a base salt. If it is the result of a reaction between a strong acid and a strong base, the result is a neutral salt. Weak acids reacted with weak bases can produce ionic compounds with both the conjugate base ion and conjugate acid ion, such as ammonium acetate.
Metal aqua ions are often involved in the formation of complexes. The reaction may be written as pM x+ (aq) + qL y− → [M p L q] (px-qy)+ In reality this is a substitution reaction in which one or more water molecules from the first hydration shell of the metal ion are replaced by ligands, L. The complex is described as an inner-sphere complex.
The halogens can all react with metals to form metal halides according to the following equation: 2M + nX 2 → 2MX n. where M is the metal, X is the halogen, and MX n is the metal halide. Sample of silver chloride. In practice, this type of reaction may be very exothermic, hence impractical as a preparative technique.
The Heck reaction (also called the Mizoroki–Heck reaction) [1] is the chemical reaction of an unsaturated halide (or triflate) with an alkene in the presence of a base and a palladium catalyst to form a substituted alkene. It is named after Tsutomu Mizoroki and Richard F. Heck.
Metal chlorates can be prepared by adding chlorine to hot metal hydroxides like KOH: 3 Cl 2 + 6 KOH → 5 KCl + KClO 3 + 3 H 2 O. In this reaction, chlorine undergoes disproportionation, both reduction and oxidation. Chlorine, oxidation number 0, forms chloride (Cl −; oxidation number −1) and chlorate(V) (ClO − 3; oxidation number +5
In chemistry, a counterion (sometimes written as "counter ion", pronounced as such) is the ion that accompanies an ionic species in order to maintain electric neutrality. In table salt (NaCl, also known as sodium chloride) the sodium ion (positively charged) is the counterion for the chloride ion (negatively charged) and vice versa.