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Also called the probability factor, the steric factor is defined as the ratio between the experimental value of the rate constant and the one predicted by collision theory. It can also be defined as the ratio between the pre-exponential factor and the collision frequency, and it is most often less than unity. Physically, the steric factor can ...
The rate for a bimolecular gas-phase reaction, A + B → product, predicted by collision theory is [6] = = ()where: k is the rate constant in units of (number of molecules) −1 ⋅s −1 ⋅m 3.
In a series of papers he: was one of the first to mention some of the failings of the triboelectric series, also showing that heat had a major effect on tribocharging; [29] analyzed in detail where different materials would fall in a triboelectric series, at the same time pointing out anomalies; [1] separately analyzed glass and solid elements ...
The COR is a property of a pair of objects in a collision, not a single object. If a given object collides with two different objects, each collision has its own COR. When a single object is described as having a given coefficient of restitution, as if it were an intrinsic property without reference to a second object, some assumptions have been made – for example that the collision is with ...
This number is known as the Coulomb logarithm and is designated by either or . It is the factor by which small-angle collisions are more effective than large-angle collisions. The Coulomb logarithm was introduced independently by Lev Landau in 1936 [1] and Subrahmanyan Chandrasekhar in 1943. [2]
Collision frequency describes the rate of collisions between two atomic or molecular species in a given volume, per unit time. In an ideal gas , assuming that the species behave like hard spheres, the collision frequency between entities of species A and species B is: [ 1 ]
For example, the mobility of the sodium ion (Na +) in water at 25 °C is 5.19 × 10 −8 m 2 /(V·s). [1] This means that a sodium ion in an electric field of 1 V/m would have an average drift velocity of 5.19 × 10 −8 m/s. Such values can be obtained from measurements of ionic conductivity in solution.
Then the electron mobility μ is defined as =. Electron mobility is almost always specified in units of cm 2 /(V⋅s). This is different from the SI unit of mobility, m 2 /(V⋅s). They are related by 1 m 2 /(V⋅s) = 10 4 cm 2 /(V⋅s). Conductivity is proportional to the product of mobility and carrier concentration. For example, the same ...