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A spectral line is a weaker or stronger region in an otherwise uniform and continuous spectrum. It may result from emission or absorption of light in a narrow frequency range, compared with the nearby frequencies. Spectral lines are often used to identify atoms and molecules.
Spectral line shape or spectral line profile describes the form of an electromagnetic spectrum in the vicinity of a spectral line – a region of stronger or weaker intensity in the spectrum. Ideal line shapes include Lorentzian , Gaussian and Voigt functions, whose parameters are the line position, maximum height and half-width. [ 1 ]
The pseudo-Voigt profile (or pseudo-Voigt function) is an approximation of the Voigt profile V(x) using a linear combination of a Gaussian curve G(x) and a Lorentzian curve L(x) instead of their convolution. The pseudo-Voigt function is often used for calculations of experimental spectral line shapes.
The spectral centroid of a signal is the midpoint of its spectral density function, i.e. the frequency that divides the distribution into two equal parts. The spectral edge frequency (SEF), usually expressed as "SEF x", represents the frequency below which x percent of the total power of a given signal are located; typically, x is in the range ...
A related phenomenon is the appearance of strong harmonics when a sinusoidal signal (which has the ultimate "discrete spectrum", consisting of a single spectral line) is modified by a non-linear filter; for example, when a pure tone is played through an overloaded amplifier, [17] or when an intense monochromatic laser beam goes through a non ...
The equivalent width of a spectral line is a measure of the area of the line on a plot of intensity versus wavelength in relation to underlying continuum level. It is found by forming a rectangle with a height equal to that of continuum emission, and finding the width such that the area of the rectangle is equal to the area in the spectral line.
All three types of measures are invariant under linear operations. Let H ac be the subspace consisting of vectors whose spectral measures are absolutely continuous with respect to the Lebesgue measure. Define H pp and H sc in analogous fashion. These subspaces are invariant under T. For example, if h ∈ H ac and k = T h.
Zeeman effect on a sunspot spectral line George Ellery Hale was the first to notice the Zeeman effect in the solar spectra, indicating the existence of strong magnetic fields in sunspots. Such fields can be quite high, on the order of 0.1 tesla or higher.