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In the food industry and biochemistry, interesterification (IE) is a process that rearranges the fatty acids of a fat product, typically a mixture of triglycerides.The process implies breaking and reforming the ester bonds C–O–C that connect the fatty acid chains to the glycerol hubs of the fat molecules.
FAME are typically produced by an alkali-catalyzed reaction between fats and methanol in the presence of base such as sodium hydroxide, sodium methoxide [2] or potassium hydroxide. One reason for using FAME (fatty acid methyl esters) in biodiesel production, rather than free fatty acids, is to mitigate the potential corrosion they can cause to ...
Lipid peroxidation, or lipid oxidation, is a complex chemical process that leads to oxidative degradation of lipids, [1] resulting in the formation of peroxide and hydroperoxide derivatives. [2] It occurs when free radicals , specifically reactive oxygen species (ROS), interact with lipids within cell membranes , typically polyunsaturated fatty ...
This would lead to undesirable side reactions, and thus falsifying a result consumption of bromine. [ 8 ] For educational purposes, Simurdiak et al. (2016) [ 3 ] suggested the use of pyridinium tribromide as bromination reagent which is more safer in chemistry class and reduces drastically the reaction time.
The peroxide value is defined as the amount of peroxide oxygen per 1 kilogram of fat or oil. Traditionally this was expressed in units of milliequivalents, although in SI units the appropriate option would be in millimoles per kilogram (N.B. 1 milliequivalents = 0.5 millimole; because 1 mEq of O 2 =1 mmol/2 of O 2 =0.5 mmol of O 2, where 2 is valence).
The chemical substance may be a fat, oil, natural or synthetic ester, or other polyol. [ 3 ] ASTM D 1957 [ 4 ] and ASTM E222-10 [ 5 ] describe several versions of this method of determining hydroxyl value.
Ethanol is the most used because of its low cost, however, greater conversions into biodiesel can be reached using methanol. Although the transesterification reaction can be catalyzed by either acids or bases, the base-catalyzed reaction is more common. This path has lower reaction times and catalyst cost than those acid catalysis.
Another method of termination is the reaction between a lipid radical and a lipid peroxide, or the combination of two lipid peroxide molecules, resulting in stable nonreactive molecules. [ 4 ] [ 5 ] Reinforced lipids that become part of the membrane if consumed with heavy isotope diet also inhibit peroxidation.