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Scattering by graphene's acoustic phonons intrinsically limits room temperature mobility to 200 000 cm 2 ⋅V −1 ⋅s −1 at a carrier density of 10 12 cm −2, [12] [13] 10 × 10 6 times greater than copper. [14] The corresponding resistivity of graphene sheets would be 10 −6 Ω⋅cm.
Graphene is the only form of carbon (or solid material) in which every atom is available for chemical reaction from two sides (due to the 2D structure). Atoms at the edges of a graphene sheet have special chemical reactivity. Graphene has the highest ratio of edge atoms of any allotrope. Defects within a sheet increase its chemical reactivity. [1]
Graphene (/ ˈ ɡ r æ f iː n /) [1] is a carbon allotrope consisting of a single layer of atoms arranged in a honeycomb planar nanostructure. [2] [3] The name "graphene" is derived from "graphite" and the suffix -ene, indicating the presence of double bonds within the carbon structure.
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Doped graphene layers have also shown the similar surface plasmon effects to that of metallic thin films. [7] [8] Through the engineering of metallic substrates or nanoparticles (e.g., gold, silver and copper) with graphene, the plasmonic properties of the hybrid structures could be tuned for improving the optoelectronic device performances.
Furthermore, as the electrons oscillate, they create an electromagnetic wave atop the graphene layer, referred to as the surface plasmon polariton wave. This would enable the antenna to operate at the lower end of the terahertz frequency, which would be more efficient than the current copper based antennas.
In 2017, researchers at Clemson Nanomaterials Institute used a graphene electrode to intercalate tetrachloroaluminate (AlCl − 4 ). [ 8 ] The team constructed batteries with aluminium anodes, pristine or modified few-layer graphene cathodes, and an ionic liquid with AlCl3 salt as the electrolyte. [ 8 ]
Bilayer graphene is a material consisting of two layers of graphene. One of the first reports of bilayer graphene was in the seminal 2004 Science paper by Geim and colleagues, [ 1 ] in which they described devices "which contained just one, two, or three atomic layers"