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The addition of phosphorus as super-phosphate enables much greater crop yields. [4] Although there is some replenishment of soil phosphorus from mineral sources and release from soil complexes by physical and biological mechanisms, the rate of re-solubilisation is too low to support modern agricultural productivity.
Phosphogypsum is a by-product from the production of phosphoric acid by treating phosphate ore with sulfuric acid according to the following reaction: Ca 5 (PO 4) 3 X + 5 H 2 SO 4 + 10 H 2 O → 3 H 3 PO 4 + 5 (CaSO 4 · 2 H 2 O) + HX where X may include OH, F, Cl, or Br
Calcium nitrate with 15,5% nitrogen and 19% calcium, reportedly holding a small share of the nitrogen fertilizer market (4% in 2007). [28] The main straight phosphate fertilizers are the superphosphates: "Single superphosphate" (SSP) consisting of 14–18% P 2 O 5, again in the form of Ca(H 2 PO 4) 2, but also phosphogypsum (CaSO 4 · 2 H 2 O).
Phosphate rich organic manure is a type of fertilizer used as an alternative to diammonium phosphate and single super phosphate. Phosphorus is required by all plants but is limited in soil, creating a problem in agriculture In many areas phosphorus must be added to soil for the extensive plant growth that is desired for crop production.
Nutrients in the soil are taken up by the plant through its roots, and in particular its root hairs.To be taken up by a plant, a nutrient element must be located near the root surface; however, the supply of nutrients in contact with the root is rapidly depleted within a distance of ca. 2 mm. [14] There are three basic mechanisms whereby nutrient ions dissolved in the soil solution are brought ...
Fertilizers with additional macronutrients (S, Ca, Mg) may add more numbers to the N-P-K ratio to indicate the amount. The additional numbers are similarly reported in the oxide mass fraction form. For example, a Polish fertilizer labeled "NPK (Ca,S) 4-12-12 (14-29)" has an equivalent of 14% soluble calcium oxide and 29% total sulfur trioxide. [6]
The phosphate ion has a molar mass of 94.97 g/mol, and consists of a central phosphorus atom surrounded by four oxygen atoms in a tetrahedral arrangement. It is the conjugate base of the hydrogen phosphate ion H(PO 4) 2−, which in turn is the conjugate base of the dihydrogen phosphate ion H 2 (PO 4) −
Controlled release fertilizers are traditional fertilizers encapsulated in a shell that degrades at a specified rate. Sulfur is a typical encapsulation material. Other coated products use thermoplastics (and sometimes ethylene-vinyl acetate and surfactants, etc.) to produce diffusion-controlled release of urea or other fertilizers.