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In chemistry, a superoxide is a compound that contains the superoxide ion, which has the chemical formula O − 2. [1] The systematic name of the anion is dioxide(1−).The reactive oxygen ion superoxide is particularly important as the product of the one-electron reduction of dioxygen O 2, which occurs widely in nature. [2]
Each oxygen atom in its peroxide ion may have a full octet of 4 pairs of electrons. [6] Superoxides are a class of compounds that are very similar to peroxides, but with just one unpaired electron for each pair of oxygen atoms (O − 2). [6] These compounds form by oxidation of alkali metals with larger ionic radii (K, Rb, Cs).
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"Oxide" itself is the dianion (anion bearing a net charge of –2) of oxygen, an O 2– ion with oxygen in the oxidation state of −2. Most of the Earth's crust consists of oxides. Even materials considered pure elements often develop an oxide coating.
SOD1 is located primarily in the cytoplasm, SOD2 in the mitochondria and SOD3 is extracellular. The first is a dimer (consists of two units), while the others are tetramers (four subunits). SOD1 and SOD3 contain copper and zinc ions, while SOD2 has a manganese ion in its reactive centre.
The doublet state requires an odd number of electrons, and so cannot occur in dioxygen without gaining or losing electrons, such as in the superoxide ion (O − 2) or the dioxygenyl ion (O + 2). The ground state of O 2 has a bond length of 121 pm and a bond energy of 498 kJ/mol. [ 3 ] It is a colourless gas with a boiling point of −183 °C ...
Singlet oxygen is a name given to several higher-energy species of molecular O 2 in which all the electron spins are paired. It is much more reactive with common organic molecules than is normal (triplet) molecular oxygen. In nature, singlet oxygen is commonly formed from water during photosynthesis, using the energy of sunlight. [38]
The dioxygenyl ion, O + 2, is a rarely-encountered oxycation in which both oxygen atoms have a formal oxidation state of + 1 / 2 . It is formally derived from oxygen by the removal of an electron: O 2 → O + 2 + e −. The energy change for this process is called the ionization energy of the oxygen molecule.