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Tetrafluoroethane (a haloalkane) is a colorless liquid that boils well below room temperature (as seen here) and can be extracted from common canned air canisters by simply inverting them during use. The haloalkanes (also known as halogenoalkanes or alkyl halides) are alkanes containing one or more halogen substituents. [1]
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The general structure is RR′C(X)C(=O)R where R is an alkyl or aryl residue and X any one of the halogens. The preferred conformation of a halo ketone is that of a cisoid with the halogen and carbonyl sharing the same plane as the steric hindrance with the carbonyl alkyl group is generally larger.
Haloalkane, or halogenoalkane, a group of chemical compounds consisting of alkanes with linked halogens (in particular, bromine-containing haloalkanes) Halomethane compounds: Halon 10001 (iodomethane) Halon 1001 (bromomethane) Halon 1011 (bromochloromethane, CH 2 BrCl) Halon 104 (carbon tetrachloride) Halon 1103 (tribromofluoromethane)
Haloalkanes are diverse in their properties, making generalizations difficult. Few are acutely toxic, but many pose risks from prolonged exposure. Some problematic aspects include carcinogenicity and liver damage (e.g., carbon tetrachloride). Under certain combustion conditions, chloromethanes convert to phosgene, which is highly toxic.
In organic chemistry, free-radical halogenation is a type of halogenation. This chemical reaction is typical of alkanes and alkyl -substituted aromatics under application of UV light . The reaction is used for the industrial synthesis of chloroform (CHCl 3 ), dichloromethane (CH 2 Cl 2 ), and hexachlorobutadiene .
See the alkane heat of formation table for detailed data. The standard enthalpy change of combustion , Δ c H ⊖ , for alkanes increases by about 650 kJ/mol per CH 2 group. Branched-chain alkanes have lower values of Δ c H ⊖ than straight-chain alkanes of the same number of carbon atoms, and so can be seen to be somewhat more stable.