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Sodium borohydride, also known as sodium tetrahydridoborate and sodium tetrahydroborate, [5] is an inorganic compound with the formula Na B H 4 (sometimes written as Na[BH 4]). It is a white crystalline solid, usually encountered as an aqueous basic solution .
Borohydride refers to the anion [B H 4] −, which is also called tetrahydridoborate, and its salts. [1] Borohydride or hydroborate is also the term used for compounds containing [BH 4− n X n ] − , where n is an integer from 0 to 3, for example cyanoborohydride or cyanotrihydroborate [BH 3 (CN)] − and triethylborohydride or ...
Sodium triacetoxyborohydride, also known as sodium triacetoxyhydroborate, commonly abbreviated STAB, is a chemical compound with the formula Na[(CH 3 COO) 3 BH]. Like other borohydrides, it is used as a reducing agent in organic synthesis. This colourless salt is prepared by protonolysis of sodium borohydride with acetic acid: [1]
Structure of a rare monomeric boron hydride, R = i-Pr. [4] The most-studied class of organoboron compounds has the formula BR n H 3−n. These compounds are catalysts, reagents, and synthetic intermediates. The trialkyl and triaryl derivatives feature a trigonal-planar boron center that is typically only weakly Lewis acidic.
Sodium cyanoborohydride is a chemical compound with the formula Na[B H 3 (C N)]. It is a colourless salt used in organic synthesis for chemical reduction including that of imines and carbonyls . Sodium cyanoborohydride is a milder reductant than other conventional reducing agents .
Chloro(pyridine)cobaloxime(III) is first reduced to Chloro(pyridine)cobaloxime(I) by sodium borohydride in alkaline solution, then an alkyl halide is added into the reaction mixture, and the desired Co-C bond is formed via a S N 2 reaction. This method can be used to produce cobaloximes containing a primary or a secondary alkyl substituent.
Ammonia borane (also systematically named ammoniotrihydroborate [citation needed]), also called borazane, is the chemical compound with the formula H 3 NBH 3.The colourless or white solid is the simplest molecular boron-nitrogen-hydride compound.
Trimethyl borate is the main precursor to sodium borohydride by its reaction with sodium hydride in the Brown-Schlesinger process: 4 NaH + B(OCH 3) 3 → NaBH 4 + 3 NaOCH 3. It is a gaseous anti-oxidant in brazing and solder flux. Otherwise, trimethyl borate has no announced commercial applications.