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Absorption spectroscopy is spectroscopy that involves techniques that measure the absorption of electromagnetic radiation, as a function of frequency or wavelength, due to its interaction with a sample. The sample absorbs energy, i.e., photons, from the radiating field.
X-ray absorption spectroscopy (XAS) is a widely used technique for determining the local geometric and/or electronic structure of matter. [1] The experiment is usually performed at synchrotron radiation facilities, which provide intense and tunable X-ray beams. Samples can be in the gas phase, solutions, or solids. [2]
Saturated absorption spectroscopy measures the transition frequency of an atom or molecule between its ground state and an excited state.In saturated absorption spectroscopy, two counter-propagating, overlapped laser beams are sent through a sample of atomic gas.
An overview of absorption of electromagnetic radiation.This example shows the general principle using visible light as a specific example. A white light source—emitting light of multiple wavelengths—is focused on a sample (the pairs of complementary colors are indicated by the yellow dotted lines).
X-ray absorption edge spectroscopy corresponds to the transition from a core-level to an unoccupied orbital or band and mainly reflects the electronic unoccupied states. EXAFS, resulting from the interference in the single scattering process of the photoelectron scattered by surrounding atoms, provides information on the local structure.
In spectroscopy, an absorption band is a range of wavelengths, frequencies or energies in the electromagnetic spectrum that are characteristic of a particular transition from initial to final state in a substance. According to quantum mechanics, atoms and molecules can only hold certain defined quantities of energy, or exist in specific states. [1]
Extended X-ray absorption fine structure (EXAFS), along with X-ray absorption near edge structure , is a subset of X-ray absorption spectroscopy . Like other absorption spectroscopies, XAS techniques follow Beer's law. The X-ray absorption coefficient of a material as a function of energy is obtained by directing X-rays of a narrow energy range ...
Atomic absorption spectroscopy (AAS) is a spectroanalytical procedure for the quantitative measurement of chemical elements. AAS is based on the absorption of light by free metallic ions that have been atomized from a sample.