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Two-dimensional chromatography is a type of chromatographic technique in which the injected sample is separated by passing through two different separation stages. Two different chromatographic columns are connected in sequence, and the effluent from the first system is transferred onto the second column. [ 1 ]
Copper-free click chemistry is a bioorthogonal reaction first developed by Carolyn Bertozzi as an activated variant of an azide alkyne Huisgen cycloaddition, based on the work by Karl Barry Sharpless et al. Unlike CuAAC, Cu-free click chemistry has been modified to be bioorthogonal by eliminating a cytotoxic copper catalyst, allowing reaction ...
Recrystallization: In analytical and synthetic chemistry work, purchased reagents of doubtful purity may be recrystallised, e.g. dissolved in a very pure solvent, and then crystallized, and the crystals recovered, in order to improve and/or verify their purity.
The axial pair lie along a common bond axis so that are related by a bond angle of 180°. The equatorial pair of ligands is situated in a plane orthogonal to the axis of the axial pair. Typically the bond distance to the axial ligands is longer than to the equatorial ligands.
Oligonucleotide synthesis is the chemical synthesis of relatively short fragments of nucleic acids with defined chemical structure ().The technique is extremely useful in current laboratory practice because it provides a rapid and inexpensive access to custom-made oligonucleotides of the desired sequence.
An orthogonal wavelet is a wavelet whose associated wavelet transform is orthogonal. That is, the inverse wavelet transform is the adjoint of the wavelet transform. If this condition is weakened one may end up with biorthogonal wavelets .
Example of a localized Wannier function of titanium in barium titanate (BaTiO3) Although, like localized molecular orbitals, Wannier functions can be chosen in many different ways, [3] the original, [1] simplest, and most common definition in solid-state physics is as follows. Choose a single band in a perfect crystal, and denote its Bloch ...
An example is the pair of sets of respectively left and right eigenvectors of a matrix, indexed by eigenvalue, if the eigenvalues are distinct. [1] A biorthogonal system in which = and ~ = ~ is an orthonormal system.