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  2. Cyclohexenone - Wikipedia

    en.wikipedia.org/wiki/Cyclohexenone

    With strong bases, the positions 4 and 6 (the two CH 2-groups of the carbonyl group and the C-C double bond adjacent) are deprotonated. Cyclohexenone is an in-vitro catalyst for a relatively mild decarboxylation of alpha amino acids .

  3. Cyclohexanedimethanol - Wikipedia

    en.wikipedia.org/wiki/Cyclohexanedimethanol

    The reaction conducted in two steps beginning with the conversion of DMT to the diester dimethyl 1,4-cyclohexanedicarboxylate (DMCD): C 6 H 4 (CO 2 CH 3) 2 + 3 H 2C 6 H 10 (CO 2 CH 3) 2. In the second step DMCD is further hydrogenated to CHDM: C 6 H 10 (CO 2 CH 3) 2 + 4 H 2C 6 H 10 (CH 2 OH) 2 + 2 CH 3 OH. A copper chromite catalyst ...

  4. Cyclohexanol - Wikipedia

    en.wikipedia.org/wiki/Cyclohexanol

    2 C 6 H 12 + O 22 C 6 H 11 OH. This process coforms cyclohexanone, and this mixture ("KA oil" for ketone-alcohol oil) is the main feedstock for the production of adipic acid. The oxidation involves radicals and the intermediacy of the hydroperoxide C 6 H 11 O 2 H. Alternatively, cyclohexanol can be produced by the hydrogenation of phenol ...

  5. Cyclohexanone - Wikipedia

    en.wikipedia.org/wiki/Cyclohexanone

    Cyclohexanone is produced by the oxidation of cyclohexane in air, typically using cobalt catalysts: [11]. C 6 H 12 + O 2 → (CH 2) 5 CO + H 2 O. This process forms cyclohexanol as a by-product, and this mixture, called "KA Oil" for ketone-alcohol oil, is the main feedstock for the production of adipic acid.

  6. 1,4-Cyclohexanedione - Wikipedia

    en.wikipedia.org/wiki/1,4-Cyclohexanedione

    1,4-Cyclohexanedione is an organic compound with the formula (CH 2) 4 (CO) 2. This white solid is one of the three isomeric cyclohexanediones . This particular diketone is used as a building block in the synthesis of more complex molecules.

  7. Dimedone - Wikipedia

    en.wikipedia.org/wiki/Dimedone

    Dimedone is an organic compound with the formula (CH 3) 2 C(CH 2) 2 (CO) 2 (CH 2). Classified as a cyclic diketone, it is a derivative of 1,3-cyclohexanedione. It is a white solid that is soluble in water, as well as ethanol and methanol. It once was used as a reagent to test for the aldehyde functional group.

  8. Cyclohexanehexone - Wikipedia

    en.wikipedia.org/wiki/Cyclohexanehexone

    [4] [5] In 1966, Howard E. Worne of Natick Chemical Industries patented compounds with formulas C 10 O 8 and C 14 O 10 , which can be described as the fusion of two or three molecules of C 6 O 6 , claimed to be produced by the action of ultraviolet radiation on a hot water solution of the parent compound.

  9. Gilman reagent - Wikipedia

    en.wikipedia.org/wiki/Gilman_reagent

    Lithium dimethylcopper (CH 3) 2 CuLi can be prepared by adding copper(I) iodide to methyllithium in tetrahydrofuran at −78 °C. In the reaction depicted below, [4] the Gilman reagent is a methylating reagent reacting with an alkyne in a conjugate addition, and the ester group forms a cyclic enone. Scheme 1. Example Gilman reagent reaction

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