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In aqueous solutions, redox potential is a measure of the tendency of the solution to either gain or lose electrons in a reaction. A solution with a higher (more positive) reduction potential than some other molecule will have a tendency to gain electrons from this molecule (i.e. to be reduced by oxidizing this other molecule) and a solution with a lower (more negative) reduction potential ...
Electrical conductivity of water samples is used as an indicator of how salt-free, ion-free, or impurity-free the sample is; the purer the water, the lower the conductivity (the higher the resistivity). Conductivity measurements in water are often reported as specific conductance, relative to the conductivity of pure water at 25 °C.
In optics, the Hagen–Rubens relation (or Hagen–Rubens formula) is a relation between the coefficient of reflection and the conductivity for materials that are good conductors. [1] The relation states that for solids where the contribution of the dielectric constant to the index of refraction is negligible, the reflection coefficient can be ...
Since metals can display multiple oxidation numbers, the exact definition of how many "valence electrons" an element should have in elemental form is somewhat arbitrary, but the following table lists the free electron densities given in Ashcroft and Mermin, which were calculated using the formula above based on reasonable assumptions about ...
The optical conductivity is most often measured in optical frequency ranges via the reflectivity of polished samples under normal incidence (in combination with a Kramers–Kronig analysis) or using variable incidence angles. [5] For samples that can be prepared in thin slices, higher precision is obtainable using optical transmission experiments.
Drude formula is derived in a limited way, namely by assuming that the charge carriers form a classical ideal gas. When quantum theory is considered, the Drude model can be extended to the free electron model, where the carriers follow Fermi–Dirac distribution. The conductivity predicted is the same as in the Drude model because it does not ...
Conductivity or specific conductance of an electrolyte solution is a measure of its ability to conduct electricity. The SI unit of conductivity is siemens per meter (S/m). Conductivity measurements are used routinely in many industrial and environmental applications as a fast, inexpensive and reliable way of measuring the ionic content in a ...
Also called chordal or DC resistance This corresponds to the usual definition of resistance; the voltage divided by the current R s t a t i c = V I. {\displaystyle R_{\mathrm {static} }={V \over I}.} It is the slope of the line (chord) from the origin through the point on the curve. Static resistance determines the power dissipation in an electrical component. Points on the current–voltage ...