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The x-coordinates of the red circles are stationary points; the blue squares are inflection points. In mathematics, a critical point is the argument of a function where the function derivative is zero (or undefined, as specified below). The value of the function at a critical point is a critical value. [1]
The critical point remains a point on the surface even on a 3D phase diagram. An orthographic projection of the 3D p–v–T graph showing pressure and temperature as the vertical and horizontal axes collapses the 3D plot into the standard 2D pressure–temperature diagram. When this is done, the solid–vapor, solid–liquid, and liquid ...
Critical point may refer to: Critical phenomena in physics; Critical point (mathematics), in calculus, a point where a function's derivative is either zero or nonexistent; Critical point (set theory), an elementary embedding of a transitive class into another transitive class which is the smallest ordinal which is not mapped to itself
In thermodynamics, a critical point (or critical state) is the end point of a phase equilibrium curve. One example is the liquid–vapor critical point, the end point of the pressure–temperature curve that designates conditions under which a liquid and its vapor can coexist.
In higher dimensions, a critical point of a scalar valued function is a point at which the gradient is zero. The second derivative test can still be used to analyse critical points by considering the eigenvalues of the Hessian matrix of second partial derivatives of the function at the critical point. If all of the eigenvalues are positive ...
As the temperature and pressure approach the critical point, the properties of the liquid and gas become progressively more similar. At the critical point, the liquid and gas become indistinguishable. Above the critical point, there are no longer separate liquid and gas phases: there is only a generic fluid phase referred to as a supercritical ...
David R. Lide (ed), CRC Handbook of Chemistry and Physics, 85th Edition, online version. CRC Press. Boca Raton, Florida, 2003; Section 6, Fluid Properties; Critical Constants. Also agrees with Celsius values from Section 4: Properties of the Elements and Inorganic Compounds, Melting, Boiling, Triple, and Critical Point Temperatures of the Elements
The critical point is described by a conformal field theory. According to the renormalization group theory, the defining property of criticality is that the characteristic length scale of the structure of the physical system, also known as the correlation length ξ, becomes infinite. This can happen along critical lines in phase space.