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The nitride anion, N 3-ion, is very elusive but compounds of nitride are numerous, although rarely naturally occurring. Some nitrides have a found applications, [1] such as wear-resistant coatings (e.g., titanium nitride, TiN), hard ceramic materials (e.g., silicon nitride, Si 3 N 4), and semiconductors (e.g., gallium nitride, GaN).
Sodium azide NaN 3 is the propellant in automobile airbags. It decomposes on heating to give nitrogen gas, which is used to quickly expand the air bag: [7] 2 NaN 3 → 2 Na + 3 N 2. Heavy metal azides, such as lead azide, Pb(N 3) 2, are shock-sensitive detonators which violently decompose to the corresponding metal and nitrogen, for example: [8]
Ionic radius, r ion, is the radius of a monatomic ion in an ionic crystal structure. Although neither atoms nor ions have sharp boundaries, they are treated as if they were hard spheres with radii such that the sum of ionic radii of the cation and anion gives the distance between the ions in a crystal lattice.
The net charge of an ion is not zero because its total number of electrons is unequal to its total number of protons. A cation is a positively charged ion with fewer electrons than protons [2] (e.g. K + (potassium ion)) while an anion is a negatively charged ion with more electrons than protons. [3] (e.g. Cl − (chloride ion) and OH − ...
In the NO − 3 anion, the oxidation state of the central nitrogen atom is V (+5). This corresponds to the highest possible oxidation number of nitrogen. Nitrate is a potentially powerful oxidizer as evidenced by its explosive behaviour at high temperature when it is detonated in ammonium nitrate (NH 4 NO 3), or black powder, ignited by the shock wave of a primary explosive.
Lithium nitride is prepared by direct reaction of elemental lithium with nitrogen gas: [2]. 6 Li + N 2 → 2 Li 3 N. Instead of burning lithium metal in an atmosphere of nitrogen, a solution of lithium in liquid sodium metal can be treated with N 2.
Sodium nitride is the inorganic compound with the chemical formula Na 3 N. In contrast to lithium nitride and some other nitrides , sodium nitride is an extremely unstable alkali metal nitride . It can be generated by combining atomic beams of sodium and nitrogen deposited onto a low-temperature sapphire substrate. [ 1 ]
In chemistry, the pentazenium cation (also known as pentanitrogen) is a positively-charged polyatomic ion with the chemical formula N + 5 and structure N−N−N−N−N.Together with solid nitrogen polymers and the azide anion, it is one of only three poly-nitrogen species obtained in bulk quantities.