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Isobutane is the principal feedstock in alkylation units of refineries. Using isobutane, gasoline-grade "blendstocks" are generated with high branching for good combustion characteristics. Typical products created with isobutane are 2,4-dimethylpentane and especially 2,2,4-trimethylpentane. [7] Typical acid-catalyzed route to 2,4-dimethylpentane.
However, in many European countries, this tax break is often compensated by a much higher annual tax on cars using LPG than on cars using petrol or fuel-oil. Propane is the third most widely used motor fuel in the world. 2013 estimates are that over 24.9 million vehicles are fueled by propane gas worldwide.
Several types of valve connections for propane, butane, and LPG containers exist for transport and storage, sometimes with overlapping usage and applications, and there are major differences in usage between different countries. Even within a single country more than one type can be in use for a specific application.
Unreacted isobutane is recovered and recycled back to the reaction section to mix with the olefin feed. Propane is a major product of the distillation process. Some amount of n-butane that has entered with the feed is also withdrawn as a side product. Propane and butane that have not been separated from the treated olefin pass through the unit.
Propane is the number one alternative fuel in the world and offers an abundance of supply, liquid storage at low pressure, an excellent safety record and large cost savings when compared to traditional fuels. [57] Propane delivers an octane rating between 104 and 112 [58] depending
The operating pressure for butane is lower than operating pressures for halomethanes such as Freon-12 (R-12). Hence, R-12 systems, such as those in automotive air conditioning systems, when converted to pure butane, will function poorly. Instead, a mixture of isobutane and propane is used to give cooling system performance comparable to R-12. [28]
The boiling and melting points of n-butane and isobutane are available in the 67th edition of the CRC as follows (celsius scale). No. 3672 n-butane b.p.: -0.5, m.p.: -138. No. 3808 isobutane b.p.: -11.7, m.p.: -159.4 This issue came up (for me) as I have my students look up these values as part of a laboratory exercise.
Hydrocarbon refrigerants (a propane/isobutane blend) were also used extensively in mobile air conditioning systems in Australia, the US and many other countries, as they had excellent thermodynamic properties and performed particularly well in high ambient temperatures.