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Acidity of diethyl malonate, a 1,3-dicarbonyl compound. The central carbon in 1,3-dicarbonyl compound is known as an activated methylene group. This is because, owing to the structure, the carbon is especially acidic and can easily be deprotonated to form a methylene group. [4]
Methylene spontaneously autopolymerises to form various excited oligomers, the simplest of which, is the excited form of the alkene ethylene. The excited oligomers, decompose rather than decay to a ground state. For example, the excited form of ethylene decomposes to acetylene and atomic hydrogen. [10] 2 CH 2 → H 2 CCH * 2 → HCCH + 2 H
In organic chemistry, a methyl group is an alkyl derived from methane, containing one carbon atom bonded to three hydrogen atoms, having chemical formula CH 3 (whereas normal methane has the formula CH 4). In formulas, the group is often abbreviated as Me. This hydrocarbon group occurs in many organic compounds. It is a very stable group in ...
The general formula is R−:C−R' or R=C: where the R represents substituents or hydrogen atoms. The term "carbene" may also refer to the specific compound :CH 2, also called methylene, the parent hydride from which all other carbene compounds are formally derived. [1] [2]
A cycloalkyl group is derived from a cycloalkane by removal of a hydrogen atom from a ring and has the general formula −C n H 2n−1. [2] Typically an alkyl is a part of a larger molecule. In structural formulae, the symbol R is used to designate a generic (unspecified) alkyl group. The smallest alkyl group is methyl, with the formula −CH 3 ...
Halogenating a hydrocarbon produces something that is not a hydrocarbon. It is a very common and useful process. Hydrocarbons with the same molecular formula but different structural formulae are called structural isomers. [1]: 625 As given in the example of 3-methylhexane and its higher homologues, branched hydrocarbons can be chiral.
Methyl radical is an organic compound with the chemical formula CH • 3 (also written as [CH 3] •). It is a metastable colourless gas, which is mainly produced in situ as a precursor to other hydrocarbons in the petroleum cracking industry. It can act as either a strong oxidant or a strong reductant, and is quite corrosive to metals.
Both industrially and in the laboratory, propionaldehyde has primary application as a chemical building block. [2]: 4 [4] It is predominantly used as a precursor to trimethylolethane (CH 3 C(CH 2 OH) 3) through a condensation reaction with formaldehyde. This triol is an important intermediate in the production of alkyd resins.