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Phase transitions (phase changes) that help describe polymorphism include polymorphic transitions as well as melting and vaporization transitions. According to IUPAC, a polymorphic transition is "A reversible transition of a solid crystalline phase at a certain temperature and pressure (the inversion point) to another phase of the same chemical composition with a different crystal structure."
A three-component compatibility diagram will depict the stable phase of each pure component as the point at each corner of a ternary diagram. Additional points in the diagram represent other pure phases, and lines connecting pairs of these points represent compositions at which the two phases are the only phases present.
Polyamorphism may apply to all amorphous states, i.e. glasses, other amorphous solids, supercooled liquids, ordinary liquids or fluids. A liquid–liquid transition however, is one that occurs only in the liquid state (red line in the phase diagram, top right).
Polymorphism is the occurrence of multiple crystalline forms of a material. It is found in many crystalline materials including polymers, minerals, and metals. According to Gibbs' rules of phase equilibria, these unique crystalline phases are dependent on intensive variables such as pressure and temperature.
McMillan's model, proposed by William McMillan, [70] is an extension of the Maier–Saupe mean field theory used to describe the phase transition of a liquid crystal from a nematic to a smectic A phase. It predicts that the phase transition can be either continuous or discontinuous depending on the strength of the short-range interaction ...
For example, out of hot water, metastable, fibrous crystals of benzamide appear first, only later to spontaneously convert to the more stable rhombic polymorph. A dramatic example is phosphorus , which upon sublimation first forms the less stable white phosphorus, which only slowly polymerizes to the red allotrope .
The black crystal is garnet, the pink-orange-yellow colored strands are muscovite mica, and the brown crystals are biotite mica. The grey and white crystals are quartz and (limited) feldspar. Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture.
A melting point phase diagram may be constructed by slow heating of the slide under a microscope and observation of the melting points of the various portions of the slide. For a simple binary phase diagram, if one eutectic point is observed then the substances do not form a cocrystal. If two eutectic points are observed, then the composition ...