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  2. Xenon difluoride - Wikipedia

    en.wikipedia.org/wiki/Xenon_difluoride

    XeF 2 can act as a ligand in coordination complexes of metals. [1] For example, in HF solution: Mg(AsF 6) 2 + 4 XeF 2 → [Mg(XeF 2) 4](AsF 6) 2. Crystallographic analysis shows that the magnesium atom is coordinated to 6 fluorine atoms. Four of the fluorine atoms are attributed to the four xenon difluoride ligands while the other two are a ...

  3. Xenon compounds - Wikipedia

    en.wikipedia.org/wiki/Xenon_compounds

    Xenon reversibly complexes gaseous M(CO) 5, where M=Cr, Mo, or W. p-block metals also bind noble gases: XeBeO has been observed spectroscopically and both XeBeS and FXeBO are predicted stable. [27] The compound Xe 2 Sb 2 F 11 contains a Xe–Xe bond, the longest element-element bond known (308.71 pm = 3.0871 Å). [28]

  4. Xenon oxydifluoride - Wikipedia

    en.wikipedia.org/wiki/Xenon_oxydifluoride

    Xenon oxydifluoride is an inorganic compound with the molecular formula XeOF 2.The first definitive isolation of the compound was published on 3 March 2007, producing it by the previously-examined route of partial hydrolysis of xenon tetrafluoride.

  5. Xenon hexafluoride - Wikipedia

    en.wikipedia.org/wiki/Xenon_hexafluoride

    The structure of XeF 6 required several years to establish in contrast to the cases of XeF 2 and XeF 4.In the gas phase the compound is monomeric. VSEPR theory predicts that due to the presence of six fluoride ligands and one lone pair of electrons the structure lacks perfect octahedral symmetry, and indeed electron diffraction combined with high-level calculations indicate that the compound's ...

  6. Three-center four-electron bond - Wikipedia

    en.wikipedia.org/wiki/Three-center_four-electron...

    [7] [8] While Lewis supported the viewpoint of expanded octet, invoking s-p-d hybridized orbitals and maintaining 2c–2e bonds between neighboring atoms, Langmuir instead opted for maintaining the octet rule, invoking an ionic basis for bonding in hypervalent compounds (see Hypervalent molecule, valence bond theory diagrams for PF 5 and SF 6). [9]

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  9. Surface properties of transition metal oxides - Wikipedia

    en.wikipedia.org/wiki/Surface_properties_of...

    The cationic metal centres act as Lewis acid sites while the anionic oxygen centres act as Lewis bases. Surface hydroxyl groups can serve as Brønsted acid or base sites as they can give up or accept a proton. [14] The surface of most metal oxides will be, to some extent, hydroxylated under normal conditions when water vapor is present. [15]

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