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o-Xylene (ortho-xylene) is an aromatic hydrocarbon with the formula C 6 H 4 (CH 3) 2, with two methyl substituents bonded to adjacent carbon atoms of a benzene ring (the ortho configuration). It is a constitutional isomer of m -xylene and p -xylene , the mixture being called xylene or xylenes.
Xylene is used in the laboratory to make baths with dry ice to cool reaction vessels, [17] and as a solvent to remove synthetic immersion oil from the microscope objective in light microscopy. [18] In histology, xylene is the most widely used clearing agent. [19] Xylene is used to remove paraffin from dried microscope slides prior to staining.
S o solid? J/(mol K) Heat capacity, c p? J/(mol K) Liquid properties Std enthalpy change of formation, Δ f H o liquid: −24.4 kJ/mol Standard molar entropy, S o liquid: 247 J/(mol K) Enthalpy of combustion, Δ c H o: −4552 kJ/mol Heat capacity, c p: 187.0 J/(mol K) at 25°C Gas properties Std enthalpy change of formation, Δ f H o gas: 19.0 ...
A more modern synthesis is similar: the hydrolysis of the related tetrabromo-o-xylene using potassium oxalate, followed by purification by steam distillation. [2] The reactivity of OPA is complicated by the fact that in water it forms both a mono- and dihydrate, C 6 H 4 (CHO)(CH(OH) 2) and C 6 H 4 (CH(OH)) 2 O, respectively. Its reactions with ...
Cycloadditions of these o-xylylenes provides a pathway to acenes. [10] The diene unit formed by the two exocyclic alkene units of the ortho isomer can serve as a ligand in coordination complexes. For example, reaction of α,α'-dibromo-o-xylene with iron carbonyls affords low yields of the xylylene complex Fe(CO) 3 [η 4-C 6 H 4 (CH 2) 2].
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Phthalonitrile is produced industrially in a single-stage continuous process, by the ammoxidation of o-xylene at 480 °C. The reaction is catalyzed by vanadium oxide-antimony-oxide in a fluidized bed reactor. [2] Phthalonitrile was first described in 1896 by Johannes Pinnow.
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